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14275-61-7 - trans-1,2-Bis(tri-n-butylstannyl)ethylene, 96% - L20130 - Alfa Aesar

L20130 trans-1,2-Bis(tri-n-butylstannyl)ethylene, 96%

CAS Number
14275-61-7
Synonyms

Size Price ($) Quantity Availability
1g 99.90
5g 370.40
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trans-1,2-Bis(tri-n-butylstannyl)ethylene, 96%

MDL
MFCD01631299

Chemical Properties

Formula
C26H56Sn2
Formula Weight
606.15
Boiling Point
185°/0.01mm
Density
1.140
Refractive Index
1.5020
Sensitivity
Air & Moisture Sensitive
Solubility
Miscible with terahydrofuran and dimethyl formamide. Slightly miscible with water.

Applications

trans-1,2-Bis(tri-n-butylstannyl)ethylene is used as an intermediate in organic synthesis. It is also employed in the synthesis of gamma, delta-alkynones.

Notes

Store in a cool place. Incompatible with strong oxidizing agents.

Literature References

Liu, Y.; Liu, Z.; Luo, H.; Xie, X.; Ai, L.; Ge, Z.; Yu, G.; Liu, Y. Benzothieno [2, 3-b] thiophene semiconductors: synthesis, characterization and applications in organic field-effect transistors. J. Mater. Chem. 2014, 2 (41), 8804-8810.

Kim, J.; Han, A. R.; Hong, J.; Kim, G.; Lee, J.; Shin, T. J.; Oh, J. H.; Yang, C. Ambipolar Semiconducting Polymers with π-Spacer Linked Bis-Benzothiadiazole Blocks as Strong Accepting Units. Chem. Mater. 2014, 26 (17), 4933-4942.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H312-H315-H319-H372-H400-H410

Fatal if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Precautionary Statements: P260-P273-P280-P301+P310-P305+P351+P338-P362-P312-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3613803
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

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