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L20150 3-Bromopropionaldehyde dimethyl acetal, stab., tech. 90%

CAS Number
36255-44-4
Synonyms
1-Bromo-3,3-dimethoxypropane

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Bulk/Specialty

3-Bromopropionaldehyde dimethyl acetal, stab., tech. 90%

MDL
MFCD00013245
EINECS
252-936-6

Chemical Properties

Formula
C5H11BrO2
Formula Weight
183.04
Boiling Point
58-60°/17mm
Flash Point
45°(113°F)
Density
1.341
Refractive Index
1.4470
Storage & Sensitivity
Keep Cold.
Solubility
Not miscible or difficult to mix with water.

Applications

3-Bromopropionaldehyde dimethyl acetal was used in the synthesis of spiro cyclobutanones.

Notes

Store under refrigerated condition. Store away from oxidizing agents and protect from heat.

Literature References

Oh HS and Cha JK. Radical cyclization-fragmentation of ω-haloalkyl cyclobutanones: a modular approach to medium-sized carbocycles. Tetrahedron Asymmetry. 2003,14(19), 2911-2917

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H302-H315-H319-H335

Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P312-P330-P332+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
1697640
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2911.00
TSCA
No

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