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36255-44-4 - 3-Bromopropionaldehyde dimethyl acetal, stab., tech. 90% - 1-Bromo-3,3-dimethoxypropane - L20150 - Alfa Aesar

L20150 3-Bromopropionaldehyde dimethyl acetal, stab., tech. 90%

CAS Number
36255-44-4
Synonyms
1-Bromo-3,3-dimethoxypropane

Size Price ($) Quantity Availability
5g 67.14
25g 284.28
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3-Bromopropionaldehyde dimethyl acetal, stab., tech. 90%

MDL
MFCD00013245
EINECS
252-936-6

Chemical Properties

Formula
C5H11BrO2
Formula Weight
183.04
Boiling Point
58-60°/17mm
Flash Point
45°(113°F)
Density
1.341
Refractive Index
1.4470
Solubility
Not miscible or difficult to mix with water.

Applications

3-Bromopropionaldehyde dimethyl acetal was used in the synthesis of spiro cyclobutanones.

Notes

Store under refrigerated condition. Store away from oxidizing agents and protect from heat.

Literature References

Oh HS and Cha JK. Radical cyclization-fragmentation of ω-haloalkyl cyclobutanones: a modular approach to medium-sized carbocycles. Tetrahedron Asymmetry. 2003,14(19), 2911-2917

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
1697640
Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2911.00
TSCA
No

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