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60876-70-2 - 1-Bromo-4-tert-butoxybenzene, 98% - 4-tert-Butoxybromobenzene - L20158 - Alfa Aesar

L20158 1-Bromo-4-tert-butoxybenzene, 98%

CAS Number
60876-70-2
Synonyms
4-tert-Butoxybromobenzene

Size Price ($) Quantity Availability
5g 110.21
25g 366.77
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1-Bromo-4-tert-butoxybenzene, 98%

MDL
MFCD00792676
EINECS
000-000-0

Chemical Properties

Formula
C10H13BrO
Formula Weight
229.12
Boiling Point
63-65°/0.4mm
Refractive Index
1.5270
Solubility
Not miscible or difficult to mix in water.

Applications

It is used in the stereoselective synthesis of four stereoisomers of β-Methoxytyrosine, a component of callipeltin A.

Notes

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literature References

Bryan Li, et al. Aqueous Phosphoric Acid as a Mild Reagent for Deprotection of tert-Butyl Carbamates, Esters, and Ethers.J. Org. Chem.,2006,71(24), 9045-9050.

Darren B. Hansen, et al. Stereoselective Synthesis of Four Stereoisomers of β-Methoxytyrosine, a Component of Callipeltin A.J. Org. Chem.,2005,70(8), 3120-3126.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319

Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P302+P352

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: IF ON SKIN: Wash with plenty of soap and water.

Other References

Beilstein
2516411
Harmonized Tariff Code
2909.30
TSCA
No

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