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74181-34-3 - 2,2-Dimethyl-1,3-dioxan-5-one, tech. 90% - L20177 - Alfa Aesar

L20177 2,2-Dimethyl-1,3-dioxan-5-one, tech. 90%

CAS Number
74181-34-3
Synonyms

Size Price ($) Quantity Availability
250mg 53.90
1g 156.00
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2,2-Dimethyl-1,3-dioxan-5-one, tech. 90%

MDL
MFCD00671514

Chemical Properties

Formula
C6H10O3
Formula Weight
130.15
Boiling Point
40-46°/14mm
Refractive Index
1.4315
Sensitivity
Air & Moisture Sensitive
Solubility
Miscible with water and most organic solvents.

Applications

2,2-Dimethyl-1,3-dioxan-5-one is used in the preparation of 2,2-dimethyl-[1,3]dioxan-5-ol by reducing with lithium aluminum hydride. It is also used in the annulation of bete-(hetero)aryl-alfa-nitro-alfa,beta-enals.

Notes

Incompatible with oxidizing agents. Air, moisture and heat sensitive.

Literature References

Yu, N.; Han, S.; Yu, H. The 4,5-methano-l-proline as a chiral organocatalysts in direct asymmetric aldol reactions. Tetrahedron 2015, 71 (28), 4665-4669.

Vizcaíno-Milla, P.; Sansano, J. M.; Nájera, C.; Fiser, B.; Gómez-Bengoa, E. Pyrimidine-Derived Prolinamides as Recoverable Bifunctional Organocatalysts for Enantioselective Inter- and Intramolecular Aldol Reactions under Solvent-Free Conditions. Eur. J. Org. Chem. 2015, 2015 (12), 2614-2621.

Other References

Beilstein
3061933
Harmonized Tariff Code
2914.69
TSCA
No

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