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7486-35-3 - Tri-n-butyl(vinyl)tin, 96% - Tri-n-butylstannylethylene - Tri-n-butyl(vinyl)stannane - L20215 - Alfa Aesar

L20215 Tri-n-butyl(vinyl)tin, 96%

CAS Number
7486-35-3
Synonyms
Tri-n-butylstannylethylene
Tri-n-butyl(vinyl)stannane

Size Price ($) Quantity Availability
1g 34.00
5g 91.60
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Tri-n-butyl(vinyl)tin, 96%

MDL
MFCD00009421
EINECS
231-291-4

Chemical Properties

Formula
C14H30Sn
Formula Weight
317.11
Boiling Point
104-106°/3.5mm
Flash Point
>110°(230°F)
Density
1.085
Refractive Index
1.4780
Solubility
Not miscible or difficult to mix in water.

Applications

Tributyl(vinyl)tin is used as a reagent in the palladium catalyzed synthesis of allyl and benzyl ethers. It is also a vinyl nucleophile for bromoacetylene and bromoaromatics.

Notes

Store away from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Literature References

Masahiro Yoshida, et al. Palladium-catalyzed ring expansion reaction of (Z)-1-(1,3-butadienyl)cyclobutanols with aryl iodides. stereospecific synthesis of (Z)-2-(3-aryl-1-propenyl)cyclopentanones.Orgc. Lett.,2004,6(12), 1979-1982.

Ernesto G Occhiato, et al. Synthesis, biological activity, and three-dimensional quantitative structure-activity relationship model for a series of benzo[c]quinolizin-3-ones, nonsteroidal inhibitors of human steroid 5alpha-reductase 1.J. Med. Chem.,2004,47(14), 3546-3560.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H312-H315-H319-H372

Toxic if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P280-P301+P310a-P305+P351+P338-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3537662
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2931.20
TSCA
No

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