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403-32-7 - 4-Fluorophenylglyoxal hydrate, 98%, dry wt. basis - L20272 - Alfa Aesar

L20272 4-Fluorophenylglyoxal hydrate, 98%, dry wt. basis

CAS Number
403-32-7
Synonyms

Size Price ($) Quantity Availability
1g 36.35
5g 127.92
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4-Fluorophenylglyoxal hydrate, 98%, dry wt. basis

MDL
MFCD01320770

Chemical Properties

Formula
C8H5FO2•xH2O
Formula Weight
152.13(anhy)
Melting point
84-88°

Literature References

Aryl glyoxals have been used in the formation of 1,5-disubstituted hydantoins and thiohydantoins; J. Heterocycl. Chem., 18, 1651 (1981); the reaction was subsequently reported to be accelerated under solvent-free conditions using microwaves: Synthesis, 75 (2002).

/n

Also find extensive use in multi-component reactions to obtain a wide variety of heterocycles including butenolides: Org. Lett., 3, 2875 (2001); oxazoles via a Passerini reaction: Liebigs Ann. Chem., 1107 (1991), and pyrazines via a four-component Ugi reaction: Synthesis, 1553 (2003).

/n

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2354778
Harmonized Tariff Code
2914.70
TSCA
No
RTECS
CY1440000

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