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2914-69-4 - (S)-(-)-3-Butyn-2-ol, 99% - L20345 - Alfa Aesar

L20345 (S)-(-)-3-Butyn-2-ol, 99%

CAS Number
2914-69-4
Synonyms

Size Price ($) Quantity Availability
250mg 56.80
1g 149.00
5g 572.00
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(S)-(-)-3-Butyn-2-ol, 99%

MDL
MFCD00190166

Chemical Properties

Formula
C4H6O
Formula Weight
70.09
Boiling Point
108-109°
Flash Point
28°(82°F)
Density
0.891
Refractive Index
1.4260
Solubility
Miscible with water.

Applications

(S)-(-)-3-Butyn-2-ol is used to prepare (S)-(-)-2-tert-butyldimethylsiloxybut-3-yne. It finds application in ruthenium-catalyzed polymerization to get helical polyacetylenes.

Notes

Incompatible with strong oxidizing agents.

Literature References

Li, N.; Wang, T. Y.; Gong, L. Z.; Zhang, L. Gold-Catalyzed Multiple Cascade Reaction of 2-Alkynylphenylazides with Propargyl Alcohols. Chem. Eur. J. 2015, 21 (9), 3585-3588.

Pal, I.; Chaudhari, S. R.; Suryaprakash, N. R. Chiral discrimination of secondary alcohols and carboxylic acids by NMR spectroscopy. Magn. Reson. Chem. 2015, 53 (2), 142-146.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310-H315-H319-H335-H226

Fatal if swallowed. Fatal in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Flammable liquid and vapour.

Precautionary Statements: P210-P261-P262-P301+P310-P303+P361+P353-P305+P351+P338-P361-P302+P350-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Gently wash with plenty of soap and water. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
4652597
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2905.29
TSCA
No

Recommended

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