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Organometallic bromides are synthesized by treating an alkyl or aryl bromide with a metal, such as lithium, magnesium, or zinc. The reactivity of these compounds varies based on the reduction potential of the metal. The reactions involving organometallic bromides are very sensitive - requiring inert atmosphere and dry solvents. The organo magnesium halides are generally referred to as Grignard reagents. The metal-carbon bond in alkyl magnesium bromides has a significant amount of ionic character.

Alkyl magnesium bromide is considered to be a hybrid of ionic and covalent Lewis structures. Alkyl magnesium bromides are sources of nucleophiles which attack the positive end of the C=O double bond. With appropriate carbonyl compounds they produce primary, secondary, and tertiary alcohols; and carboxylic acid. They add to epoxides to form carbon-carbon bonds by attacking the less substituted end of the epoxide. Organomanganese bromides, behaving like soft Grignard reagents, readily react with carbonyl compounds like aldehydes, ketones, carbon dioxide, and isocyanates, but not with esters, nitriles, or amides. The organozinc halides are used in cross-coupling reactions (known as the Negishi cross-coupling reaction), which involve the coupling of organic halides with organozinc halides, forming carbon-carbon bonds in the process. A palladium (0) species is used as the metal catalyst. For a review of organonickel reagents, see: Rosen, B. M.; Quasdorf, K. W.; Wilson, D. A.; Zhang, N.; Resmerita, A.; Garg, N. K.; Percec, V. “Nickel-Catalyzed Cross-Couplings Involving Carbon-Oxygen Bonds”, Chem. Rev., 2011, 111 (3), 1346-1416.

  • 1,1'-Dibromoferrocene, 96%
  • (1,3-Dioxolan-2-ylmethyl)zinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 1-Adamantylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 1-Dodecylmagnesium bromide, 0.5M in MeTHF
  • 1-Ethylpropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 1-Methylbutylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 1-Methylpentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 1-Naphthylmagnesium bromide, 0.5M in MeTHF
  • 2-(1,3-Dioxan-2-yl)ethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2-(1,3-Dioxolan-2-yl)ethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2,4,6-Trimethylphenylmagnesium bromide, 1M in 2-MeTHF
  • 2,4-Difluorobenzylmagnesium bromide, 0.25M in 2-MeTHF
  • 2,4-Difluorobenzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2,4-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF
  • 2,5-Dimethoxyphenylmagnesium bromide, 0.5M in 2-MeTHF
  • 2,6-Difluorobenzylmagnesium bromide, 0.25M in 2-MeTHF
  • 2,6-Difluorophenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2,6-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF
  • 2-Adamantylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2-Bromobenzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2-Cyanoethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF
  • 2-Methyl-1-naphthylmagnesium bromide, 0.25 M in 2-MeTHF
  • 2-Naphthylmagnesium bromide, 0.25M in MeTHF
  • 2-Phenylethylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2-Pyridylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2-Thiazolylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2-Thienylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 3,4,5-Trifluorophenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 3,4-Dichlorophenylmagnesium bromide, 0.50M in 2-MeTHF
  • 3,4-Difluorobenzylmagnesium bromide, 0.25M in 2-MeTHF
  • 3,4-Difluorobenzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 3,4-Difluorophenylmagnesium bromide, 0.50 M in 2-MeTHF
  • 3,4-Difluorophenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF
  • 3,4-(Methylenedioxy)phenylmagnesium bromide, 0.50 M in 2-MeTHF
  • 3,5-Difluorobenzylmagnesium bromide, 0.25M in 2-MeTHF
  • 3,5-Difluorophenylmagnesium bromide, 0.50M in 2-MeTHF
  • 3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF
  • 3,5-Dimethylphenylmagnesium bromide, 0.5M in 2-MeTHF
  • 3-Bromobenzylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 3-Butenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 3-Chloro-4-methylphenylmagnesium bromide, 0.50 M in 2-MeTHF
  • 3-Chlorophenylmagnesium bromide, 1M in MeTHF
  • 3-Cyanopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 3-(Ethoxycarbonyl)propylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 3-Fluoro-4-methylphenylmagnesium bromide, 0.50 M in 2-MeTHF
  • 3-Fluorophenylmagnesium bromide, 1M in MeTHF
  • 3-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF
  • 3-Phenylpropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles

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