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Organometallic chlorides have a significant role in organic synthesis. They have excellent selectivity and reactivity. In addition, many of them are environmental friendly and have high functional group tolerance. They are capable of effecting the transformations in an atom economic fashion and have opened up new possibilities in the total synthesis of complex molecules. Organometallic halides incorporate a variety of metals such as, Mg, Cu, Zn, Sn, Pd, Ti, Ag, etc. and have been adopted widely for industrial applications.

Highly functionalized benzylic zinc chlorides can be easily synthesized and stored for months without major loss in activity. Their reaction with plenty of electrophiles yield highly functionalized products. Polymer supported organometallic halides play an important role in solid phase synthesis.

Diorganotin carboxylates, e.g., dibutyltin dilaurate, are used as catalysts for the formation of polyurethanes, for vulcanization of silicones, and trans-esterification. Similarly, n-butyltin trichloride is used in the production of tin dioxide layers on glass bottles by chemical vapor deposition.

  • 1,10-Phenanthroline iron(II) perchlorate
  • 1-Heptylmagnesium chloride, 1M in MeTHF
  • 1-Hexylmagnesium chloride, 1M in MeTHF
  • 1-Octylmagnesium chloride, 1M in MeTHF
  • 1-Pentylmagnesium chloride, 1M in MeTHF
  • 2,3-Dichlorobenzylmagnesium chloride, 0.25M in 2-MeTHF
  • 2,4-Dichlorobenzylmagnesium chloride, 0.25M in 2-MeTHF
  • 2,5-Dichlorobenzylmagnesium chloride, 0.25M in 2-MeTHF
  • 2-Butenylmagnesium chloride, 0.5M in MeTHF
  • 2-Chloro-4-fluorobenzylmagnesium chloride, 0.25M in 2-MeTHF
  • 2-Chloro-5-(tri-n-butylstannyl)pyrimidine, 95%
  • 2-Chloro-5-(tri-n-butylstannyl)thiazole, 95%
  • 2-Chloro-6-fluorobenzylmagnesium chloride, 0.25M in 2-MeTHF
  • 2-Chlorobenzylmagnesium chloride, 0.50M in 2-MeTHF
  • 2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 2-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF
  • 2-Methoxybenzylmagnesium chloride, 0.25M in 2-MeTHF
  • 3,4-Dichlorobenzylmagnesium chloride, 0.25M in 2-MeTHF
  • 3,4-Dichlorophenylmagnesium bromide, 0.50M in 2-MeTHF
  • 3,5-Dichlorobenzylmagnesium chloride, 0.25M in 2-MeTHF
  • 3,5-Dichlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 3-Chloro-2-fluorobenzylmagnesium bromide, 0.25M in 2-MeTHF
  • 3-Chloro-5-fluorophenylmagnesium bromide, 0.50 M in 2-MeTHF
  • 3-Chlorobenzylmagnesium chloride, 0.50M in 2-MeTHF
  • 3-Chlorophenylmagnesium bromide, 1M in MeTHF
  • 3-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 3-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF
  • 3-Methoxybenzylmagnesium chloride, 0.25M in 2-MeTHF
  • 4-Chloro-2-methylphenylmagnesium bromide, 0.50 M in 2-MeTHF
  • 4-Chlorobenzylmagnesium chloride, 0.50M in 2-Me-THF
  • 4-Chlorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 4-Chlorophenylmagnesium bromide, 1M in MeTHF
  • 4-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 4-Fluorobenzylmagnesium chloride, 0.50M in 2-MeTHF
  • 4-Fluorobenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • 4-Methoxybenzylmagnesium chloride, 0.25M in 2-MeTHF
  • 5-Chloro-2-methoxyphenylmagnesium bromide, 0.50M in 2-MeTHF
  • Allylmagnesium chloride, 18% (1.7M) in THF, packaged under Argon in resealable septum cap bottles
  • Allylmagnesium chloride, 1M in MeTHF
  • alpha-Methylbenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles
  • Benzeneruthenium(II) chloride, dimer, 97%
  • Benzylmagnesium chloride, 1-2M in THF
  • Benzylmagnesium chloride, 1M in MeTHF
  • Chloropentaamminecobalt(III) chloride
  • Cyclohexylmagnesium chloride, 1M in MeTHF
  • Cyclopentylmagnesium chloride, 1M in MeTHF
  • Diethylgermanium dichloride
  • Diethyltin dichloride
  • Diisobutylaluminum chloride, 98+%, 25% w/w in hexane
  • Dimethylgermanium dichloride, 97+%

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