Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

  • Bromotrimethylsilane, 97%, stab. with copper powder or silver wire

    CAS: 2857-97-8

    [2857-97-8], C3H9BrSi, F.W. 153.09, m.p. -44°, b.p. 78-80°, f.p. -3°(26°F), d. 1.183, n20/D 1.4250, UN2920, EINECS 220-672-0, BRN 1731135, MDL MFCD00000048, TSCA Yes

    Hazard Codes: H226-H314

    Precautionary Codes: P210-P240-P241-P242-P243-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378r-P403+P233-P501c

    Silylating agent; see Appendix 4. About 104x more reactive than TMSCl in the conversion of ketones to their silyl enol ethers in the presence of Et3N: Liebigs Ann. Chem., 1718 (1980).

    Converts alcohols to alkyl bromides: Tetrahedron Lett., 4483 (1978), and acyl chlorides to acyl bromides: Synthesis, 216 (1981).

    Acetals, including MOM and THP ethers are readily cleaved, as are trityl and TBDMS ethers: Tetrahedron Lett., 25, 2515 (1984). Methyl glycosides are converted to the glycosyl bromides: Tetrahedron Lett., 22, 513 (1981).

    Epoxides, oxetanes and THF are cleaved by the reagent: Synthesis, 383 (1981), as are small ring lactones: Angew. Chem. Int. Ed., 18, 689 (1979). The cleavage of acyclic ethers and esters is markedly catalyzed by IBr: J. Org. Chem., 48, 1678 (1983).

    In combination with DMSO and Et3N, effects the bromolactonization of unsaturated acids: J. Chem. Soc., Perkin 1, 847 (1994).

    Effective catalyst for Michaelis-Arbuzov rearrangement of trivalent organophosphorus P-O-R compounds to the corresponding P=O derivatives: Org. Lett., 5, 1661 (2003).

    Compare also Iodotrimethyl­silane, A12902.

    Ferry, L.; Dorez, G.; Taguet, A.; Otazaghine, B.; Lopez-Cuesta, J. M. Chemical modification of lignin by phosphorus molecules to improve the fire behavior of polybutylene succinate. Polym. Degrad. Stab. 2015, 113, 135-143.

    Willkomm, J.; Muresan, N. M.; Reisner, E. Enhancing H2 evolution performance of an immobilised cobalt catalyst by rational ligand design. Chem. Sci. 2015, 6, 2727-2736.

    Structure image
  • Silver 2,4-pentanedionate, 98%

    CAS: 15525-64-1

    [15525-64-1], C5H7AgO2, F.W. 206.98, m.p. 100° dec., EINECS 239-568-1, MDL MFCD00000012, TSCA No

    Hazard Codes: H302-H312-H315-H319-H332-H335-H351b

    Precautionary Codes: P201-P202-P261-P264b-P270-P271-P280i-P302+P352-P304+P340-P305+P351+P338-P312-P330-P362-P403+P233-P501c

    Krenek, T.; Duchek, P.; Urbanova, M.; Pokorna, D.; Bezdicka, P.; Jakubec, I.; Pola, M.; Cerstvy, R.; Kovarik, T.; Galikova, A.; Pola, J. Thermal co-decomposition of silver acetylacetonate and tin(II) hexafluoroacetylacetonate: Formation of carbonaceous Ag/AgxSn(x = 4 and 6.7)/SnO2 composites. Thermochim. Acta 2013, 566, 92-99.

    Kim, C.; Kwon, Y.; Lee, H. Shape effect of Ag-Ni binary nanoparticles on catalytic hydrogenation aided by surface plasmons. Chem. Commun. 2015, 51 (61), 12316-12319.

    Structure image
  • Silver(I) tetraborate hydrate, 99%

    CAS: 12271-95-3

    [12271-95-3], Ag2B4O7•xH2O, F.W. 370.98(anhy), EINECS 235-548-1, MDL MFCD25372549, TSCA No

    Hazard Codes: H360-H410

    Precautionary Codes: P201-P202-P281-P308+P313-P403-P501c

    Structure image
  • Silver heptafluorobutyrate, 97%

    CAS: 3794-64-7

    [3794-64-7], C4AgF7O2, F.W. 320.90, m.p. ca 292° dec., EINECS 223-266-1, RTECS EK7875000, MDL MFCD00064197, TSCA Yes

    Hazard Codes: H303-H318

    Precautionary Codes: P280i-P305+P351+P338-P310a

    Structure image
  • Silver nanoparticles, 50nm, 0.02 mg/ml, supplied in 2mM sodium citrate, 425nm absorption

    CAS: 7440-22-4

    [7440-22-4], Liquid, MDL MFCD00003397, TSCA No

    Structure image
  • Silver nanoparticles, 100nm, 0.02 mg/ml, supplied in 2mM sodium citrate, 490nm absorption

    CAS: 7440-22-4

    [7440-22-4], Liquid, MDL MFCD00003397, TSCA Yes

    Structure image
  • Silver perchlorate monohydrate, 99.9% (metals basis)

    CAS: 14242-05-8

    [14242-05-8], AgClO4•H2O, F.W. 225.34 (207.32anhy), Crystalline, m.p. 485° dec., d. 2.800, UN1481, EINECS 232-035-4, MDL MFCD00149128, TSCA Yes

    Hazard Codes: H272-H314

    Precautionary Codes: P210-P220-P221-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378r-P403-P501c

    Kelemu, S. W.; Fitchett, C. M.; Steel, P. J. Silver perchlorate induced rearrangement of a tetraarylethene involving an apparent oxygen migration. Tetrahedron Lett. 2014, 55 (12), 2019-2021.

    Burrows, A. D.; Frost, C. G.; Mahon, M. F.; Raithby, P. R.; Richardson, C.; Stevenson, A. J. Solid state interconversion of cages and coordination networks via conformational change of a semi-rigid ligand. Chem. Commun. 2010, 46, 5064 - 5066.

    Structure image
  • Silver(I) diethyldithiocarbamate, 98+%

    CAS: 1470-61-7

    [1470-61-7], C5H10AgNS2, F.W. 256.14, m.p. 172-175°, EINECS 216-003-7, BRN 3718150, MDL MFCD00004929, TSCA Yes

    Hazard Codes: H315-H319-H335

    Precautionary Codes: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501c

    Reagent for As: Anal. Chem., 31, 1589, 1593, 2025 (1959).

    /n

    Structure image
  • Silver molybdenum oxide, 99%

    CAS: 13765-74-7

    [13765-74-7], Ag2MoO4, F.W. 375.68, Powder, m.p. 483°, d. 6.18, EINECS 237-374-1, MDL MFCD00053384, TSCA No

    Structure image
  • Silver cyclohexanebutyrate, 99% (dry wt.)

    CAS: 62638-04-4

    [62638-04-4], C10H17AgO2, F.W. 277.11, m.p. ca 255° dec., EINECS 263-667-9, MDL MFCD00036396, TSCA Yes

    Structure image
  • Silver sulfide, Premion®, 99.995% (metals basis)

    CAS: 21548-73-2

    [21548-73-2], Ag2S, F.W. 247.80, Powder, m.p. 825°, d. 7.317, EINECS 244-438-2, MDL MFCD00003406, TSCA Yes

    Goh, J. -Q.; Malola,S.; Häkkinen, H.; Akola, J. Silver Sulfide Nanoclusters and hte Superatom Model. J. Phys. Chem. C 2015, 119 (3), 1583-1590.

    Shen, H.; Jiao, X.; Oron,D.; Li, J.; Lin, H. Efficient Electron Injection in Non-toxic Silver Sulfide (Ag{2}S) Sensitized Solar Cells. J. Power Sources 2013, 240, 8-13.

    Structure image
  • Silver sulfite, 99.9%

    CAS: 13465-98-0

    [13465-98-0], Ag2O3S, F.W. 295.79, m.p. >300°, EINECS 236-714-6, MDL MFCD00064645, TSCA Yes

    Hazard Codes: H315-H319-H335

    Precautionary Codes: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

    Structure image
  • Silver chloride, Premion®, 99.997% (metals basis)

    CAS: 7783-90-6

    [7783-90-6], AgCl, F.W. 143.32, Coarse Powder, m.p. 455°, b.p. 1550°, d. 5.56, n20/D 2.071, UN1759, EINECS 232-033-3, RTECS VW3563000, MDL MFCD00003399, TSCA Yes

    Hazard Codes: H290-H410

    Precautionary Codes: P234-P390-P406b-P501c

    Gopinath, V.; Priyadarshini, S.; Priyadharsshini, N. M.; Pandian, K.; Velusamy, P. Biogenic synthesis of antibacterial silver chloride nanoparticles using leaf extracts of Cissus quadrangularis Linn. Mater. Lett. 2013, 91, 224-227.

    Putz, A. M.; Horvath, Z. E.; Gonter, K.; Almasy, L. One-pot Synthesis and Characterization of Nano-size Silver Chloride. Dig. J. Nanomater. Bios. 2015, 10 (1), 89-94.

    Structure image
  • Silver nitrite, 99% (metals basis)

    CAS: 7783-99-5

    [7783-99-5], AgNO2, F.W. 153.88, Crystalline, m.p. 140° dec., d. 4.45, UN2627, EINECS 232-041-7, MDL MFCD00003413, TSCA Yes

    Hazard Codes: H272-H302-H315-H319-H410

    Precautionary Codes: P210-P220-P221-P264b-P270-P280-P301+P312-P302+P352-P305+P351+P338-P330-P332+P313-P337+P313-P362-P370+P378r-P403-P501c

    Liu, T.; Ma, J.; Chao, D.; Zhang, P.; Liu, Q.; Shi, L.; Zhang, Z.; Zhang, G. AgNO2-mediated cleavage of the N-N bond of sulfonylhydrazones and oxygen transfer: access to fulleroisoxazolines via radical cyclization with [60]fullerene. Chem. Commun. 2015, 51 (64 ), 12775-12778.

    Kubiak, K.; Adamczyk, Z.; O?wieja, M. Kinetics of Silver Nanoparticle Deposition at PAH Monolayers: Reference QCM Results. Langmuir 2015, 31 (10), 2988-2996.

    Structure image
  • Silver iodide, 99.9% (metals basis)

    CAS: 7783-96-2

    [7783-96-2], AgI, F.W. 234.77, Crystalline, m.p. 558°, d. 5.67, UN3077, EINECS 232-038-0, RTECS VW4450000, MDL MFCD00003412, TSCA Yes

    Hazard Codes: H410

    Precautionary Codes: P403-P501c

    Fraux, G.; Doye, J. P. K. Heterogeneous ice nucleation on silver-iodide-like surfaces. J. Chem. Phys. 2014, 141, 216101.

    Grabowski, P.; Nowinski, J. L. Alpha Silver Iodide Stabilization in Mechanosynthesized AgI-Ag{2}O-M{x}O{y} Systems. Procedia Engineering 2014, 98, 86-92.

    Structure image
  • Silver carbonate, 99.5% (metals basis)

    CAS: 534-16-7

    [534-16-7], CAg2O3, F.W. 275.75, Powder, m.p. 218° dec., d. 6.08, UN3077, EINECS 208-590-3, RTECS FG0700000, MDL MFCD00003403, TSCA Yes

    Hazard Codes: H303-H318-H410

    Precautionary Codes: P270-P280-P305+P351+P338-P310-P403-P501c

    Jedinak, L.; Rush, L.; Lee, M.; Hesek, D.; Fisher, J. F.; Boggess, B.; Noll, B. C.; Mobashery, S. Use of Silver Carbonate in the Wittig Reaction. J. Org. Chem. 2013, 78 (23), 12224-12228.

    López-Cepero, J. M. Silver Carbonate Staining Reveals Mitochondrial Heterogeneity. J. Histochem. Cytochem. 2004, 52 (2), 211-216.

    Molteni, G. Silver(I) Salts as Useful Reagents in Pyrazole Synthesis. ARKIVOC 2007, (ii), 224-246.

    Structure image
  • Silver chloride, 99.9% (metals basis)

    CAS: 7783-90-6

    [7783-90-6], AgCl, F.W. 143.32, Crystalline, m.p. 455°, b.p. 1550°, d. 5.56, n20/D 2.071, UN1759, EINECS 232-033-3, RTECS VW3563000, MDL MFCD00003399, TSCA Yes

    Hazard Codes: H290-H410

    Precautionary Codes: P234-P390-P406b-P501c

    Gopinath, V.; Priyadarshini, S.; Priyadharsshini, N. M.; Pandian, K.; Velusamy, P. Biogenic synthesis of antibacterial silver chloride nanoparticles using leaf extracts of Cissus quadrangularis Linn. Mater. Lett. 2013, 91, 224-227.

    Putz, A. M.; Horvath, Z. E.; Gonter, K.; Almasy, L. One-pot Synthesis and Characterization of Nano-size Silver Chloride. Dig. J. Nanomater. Bios. 2015, 10 (1), 89-94.

    Structure image
  • Silver cyanide, 99%

    CAS: 506-64-9

    [506-64-9], CAgN, F.W. 133.84, Powder, m.p. 320° dec., d. 3.95, n20/D 1.685, UN1684, EINECS 208-048-6, RTECS VW3850000, MDL MFCD00003409, TSCA Yes

    Hazard Codes: H300-H310-H330-H410

    Precautionary Codes: P262-P264b-P270-P271-P280-P284-P302+P350-P304+P340-P310-P330-P361-P363-P403+P233-P405-P501c

    Structure image
  • Silver hexafluoroarsenate, 98+%

    CAS: 12005-82-2

    [12005-82-2], AgAsF6, F.W. 296.78, Powder, UN1557, MDL MFCD00014142, TSCA No

    Hazard Codes: H301-H331-H410

    Precautionary Codes: P201-P202-P261-P264b-P270-P271-P281-P301+P310-P304+P340-P311-P330-P403+P233-P405-P501c

    Structure image
  • Silver(I) fluoride, 98%

    CAS: 7775-41-9

    [7775-41-9], AgF, F.W. 126.87, Crystalline, m.p. 435°, b.p. ca 1150°, d. 5.852, UN3260, EINECS 231-895-8, RTECS VW4250000, MDL MFCD00003410, TSCA Yes

    Hazard Codes: H314-H410

    Precautionary Codes: P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P403+P233-P501c

    Braganza, J. F.; Bernier, L.; Botrous, I.; Collins, M. R.; Li, B.; McAlpine, I.; Ninkovic, S.; Ren, S.; Sach, N.; Tran-Dube, M.; Zeng, Q.; Zheng, B. Improved cyclization conditions to prepare 6-substituted pyrazolo[1,5-a]pyridines and pyrazolo[1,5-a]pyrazines using catalytic Ag(I) and Au(III) salts. Tetrahedron Lett. 2015, 56 (42), 5757-5760.

    Kremlev, M. M.; Mushta, A. I.; Tyrra, W.; Yagupolskii, Y. L.; Naumann, D.; Schäfer, M. Approaches to prepare perfluoroalkyl and pentafluorophenyl copper couples for cross-coupling reactions with organohalogen compounds. Dalton Trans. 2015, 44 (45), 19693-19699.

    Structure image
  • Silver hexafluorophosphate, 98%

    CAS: 26042-63-7

    [26042-63-7], AgF6P, F.W. 252.83, Powder, m.p. 102° dec., UN1759, EINECS 247-428-6, MDL MFCD00003415, TSCA Yes

    Hazard Codes: H314

    Precautionary Codes: P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P403-P501c

    Galan, R. F.; Manzano, B. R.; Otero, A.; Lanfranchi, M.; Pellinghelli, M. A. 19F and 31P NMR evidence for silver hexafluorophosphate hydrolysis in solution. New palladium difluorophosphate complexes and x-ray structure determination of [Pd(.eta.3-2-Me-C3H4)(PO2F2)(PCy3)]Inorg. Chem. 1994, 33 (10), 2309-2312.

    Hirsch, K. A.; Wilson, S. R.; Moore, J. S. Coordination Networks of 3,3‘-Dicyanodiphenylacetylene and Silver(I) Salts:? Structural Diversity through Changes in Ligand Conformation and Counter ion. Inorg. Chem. 1997, 36 (14), 2960-2968.

    Structure image
  • Potassium silver cyanide, 99.9% (metals basis), Ag 54.2%

    CAS: 506-61-6

    [506-61-6], C2AgKN2, F.W. 199.01, Powder, d. 2.36, UN1588, EINECS 208-047-0, RTECS TT5775000, MDL MFCD00036297, TSCA Yes

    Hazard Codes: H300-H310-H330-H410

    Precautionary Codes: P261-P262-P264b-P270-P271-P280-P302+P350-P304+P340-P310-P330-P361-P363-P405-P501c

    Song, Y. J.; Monnier, J. R.; Fanson, P. T.; Williams, C. T. Bimetallic Ag-Ir/Al2O3 catalysts prepared by electroless deposition: Characterization and kinetic evaluation. J. Catal. 2014, 315, 59-66.

    Liu, X.; Li, L.; Yang, Y. Z.; Huang, K. L. Doping potassium ions in silver cyanide complexes for green luminescence. Dalton Trans. 2015, 43 (10), 4086-4092.

    Structure image
  • Silver trifluoroacetate, 98%

    CAS: 2966-50-9

    [2966-50-9], C2AgF3O2, F.W. 220.88, Powder, m.p. 257-260° dec., UN3077, EINECS 221-004-0, MDL MFCD00013199, TSCA Yes

    Hazard Codes: H315-H319-H335-H400

    Precautionary Codes: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501c

    Chen, H.; Lin, H.; Chen, I.; Kuo, C. Conducting Silver Networks Based on Electrospun Poly(Methyl Methacrylate) and Silver Trifluoroacetate. ACS Appl. Mater. Interfaces 2015, 7 (18), 9479-9485.

    Wang, S.; Shen, R.; Chen, Z.; Wang, J.; Wang, D.; Li, Y. Room-Temperature Hydrogenation of Citral Catalyzed by Palladium-Silver Nanocrystals Supported on SnO2. Eur. J. Inorg. Chem. 2015, 2015 (12), 2120-2124.

    Structure image
  • Silver iodate, 98%

    CAS: 7783-97-3

    [7783-97-3], AgIO3, F.W. 282.77, Powder, m.p. >200°, d. 5.53, UN1479, EINECS 232-039-6, MDL MFCD00014150, TSCA Yes

    Hazard Codes: H272-H315-H319-H335

    Precautionary Codes: P210-P220-P221-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P370+P378r-P403+P233-P501c

    Structure image
  • Silver phosphate, 99%

    CAS: 7784-09-0

    [7784-09-0], Ag3O4P, F.W. 418.58, Powder, m.p. 849°, d. 6.37, EINECS 232-049-0, MDL MFCD00014148, TSCA Yes

    Hazard Codes: H315-H319-H335

    Precautionary Codes: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501c

    Yi, Z.; Ye, J.; Kikugawa, N.; Kako, T.; Ouyang, S.; Stuart-Williams, H.; Yang, H.; Cao, J.; Luo, W.; Li, Z.; Liu, Y.; Withers, R. L. An orthophosphate semiconductor with photooxidation properties under visible-light irradiation. Nat. Mater. 2010, 9 (7), 559-564.

    Chudobova, D.; Neijdl, L.; Gumulec, J.; Krystofova, O.; Rodrigo, M. A.; Kynicky, J.; Ruttkay-Nedecky, B.; Kopel, P.; Babula, P.; Adam, V.; Kizek, R. Complexes of Silver(I) Ions and Silver Phosphate Nanoparticles with Hyaluronic Acid and/or Chitosan as Promising Antimicrobial Agents for Vascular Grafts. Int. J. Mol. Sci. 2013, 14 (7), 13592-13614.

    Liu, J. -K.; Luo, C. -X.; Wang, J. -D.; Zhong, X. -H. Controlled Synthesis of Silver Phosphate Crystals with High Photocatalytic Activity and Bacteriostatic Activity. Cryst. Eng. Commun. 2012, 14, 8714-8721.

    Structure image

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware