[7761-88-8], AgNO3, F.W. 169.87, Liquid, UN3093, EINECS 231-853-9, MDL MFCD00003414, TSCA Yes
Hazard Codes: H272-H314-H410
Precautionary Codes: P210-P220-P221-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378r-P403+P233-P501c
Forms complexes with alkenes, used in the separation of mixtures; see, e.g.: Org. Synth. Coll., 5, 315 (1973).
Promotes the reactivity of NCS in the cleavage of 2-acylated 1,3-dithianes: Synthesis, 17 (1969), and of NBS in the 1-bromination of terminal alkynes: Angew. Chem. Int. Ed., 23, 727 (1984).
In combination with Br2 or I2 in refluxing methanol, brings about the rearrangement of acetophenones to methyl arylacetates, a reaction previously induced by thallium(III) nitrate: J. Chem. Soc., Perkin 1, 235 (1982):
The Hunsdiecker reaction of Ag salts of carboxylic acids with Br2 provides alkyl bromides with one less carbon atom which is lost as CO2; see, e.g.: Org. Synth. Coll., 3, 578 (1955). Reviews: Chem. Rev., 56, 219 (1956); Org. React., 9, 332 (1957). Compare also Mercury(II) oxide, A16157.
For the alkylation of substrates by radicals derived from decarboxylation of acids, see Trimethylacetic acid, A10776.
Brodsgaard, A.; Nielsen, T.; Molgaard, U.; Pryds, O.; Pedersen, P. Treating umbilical granuloma with topical clobetasol propionate cream at home is as effective as treating it with topical silver nitrate in the clinic. Acta Paediatr. 2015, 104 (2), 174-177.
Yang, J. Y.; Zheng, C. M.; Wang, Y. Q.; Guo, M. L. Phosphate-assisted one-pot synthesis of silver phosphate-mesoporous silica composite from sodium silicate and silver nitrate. Microporous Mesoporous Mater 2015, 204, 58-61.