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3375-31-3 - Palladium(II) acetate, Pd 45.9-48.4% - Acetic acid palladium(II) salt - Palladium diacetate - 10516 - Alfa Aesar

10516 Palladium(II) acetate, Pd 45.9-48.4%

Número CAS
3375-31-3
Nombre Alternativo
Acetic acid palladium(II) salt
Palladium diacetate

Tamaño Precio ($) Cantidad Disponibilidad
1g 66,15
5g 239,40
25g 767,70
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Palladium(II) acetate, Pd 45.9-48.4%

MDL
MFCD00012453
EINECS
222-164-4

Propiedades químicas

Fórmula
C12H18O12Pd3
Peso molecular
673.46
Formulario
Needles
Punto de fusión
ca 205° dec.
Solubilidad
Soluble as monomer in glacial acetic acid or as trimer in benzene.

Aplicaciones

Palladium(II)acetate is a catalyst of choice for a wide variety of reactions such as vinylation, Wacker process, Buchwald-Hartwig amination, carbonylation, oxidation, rearrangement of dienes (e.g., Cope rearrangement), C-C bond formation, reductive amination, etc. Precursor to Pd(0), other Pd(II) compounds of catalytic significance, and Pd nanowires.

Notas

Palladium(II) acetate decomposes to palladium on warming in alcoholic solutions, or on heating in other organic solvents. It is not compatible with strong oxidizing agents.

Referencias documentales

Zhang, S.; Shi, L.; Ding, Y. Theoretical Analysis of the Mechanism of Palladium(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of the meta-Regioselectivity. J. Am. Chem. Soc. 2011, 133 (50), 20218-20229.

Albert, J.; Granell, J.; Tavera, R. On the Mechanism of the Cyclopalladation Reaction of Benzyl-benzylidene-Amine with Palladium(II)acetate in Acetic acid. J. Organomet. Chem. 2003, 667, 192-196.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H318-H317-H413

Causes serious eye damage. May cause an allergic skin reaction. May cause long lasting harmful effects to aquatic life.

Indicaciones de precaución: P261-P273-P280-P305+P351+P338-P310-P363-P321-P333+P313-P302+P352-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Specific treatment (see label). If skin irritation or rash occurs: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,6991
Código de tarifa arancelaria unificado
2843.90
TSCA
Yes
RTECS
AJ9000000

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