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10361-44-1 - Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis) - 10657 - Alfa Aesar

10657 Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis)

Número CAS
10361-44-1
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
25g 77,90
100g 232,00
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Bismuth(III) nitrate hydrate, Puratronic®, 99.999% (metals basis)

MDL
MFCD00003460
EINECS
233-791-8

Propiedades químicas

Fórmula
Bi(NO3)3•xH2O
Peso molecular
394.99(anhy)
Formulario
Crystalline
Punto de fusión
30° dec.
Sensibilidad
Hygroscopic
Solubilidad
Slightly soluble in water; soluble in acetone, acetic acid, and glycerol. Insoluble in ethyl acetate and ethanol.

Aplicaciones

It is used in electronic ceramics and fluorescent paints. It is employed as an oxidant for selective oxidation of sulfides to sulfoxides, as a nitrating reagent for synthesizing nitro aromatic compounds, and as a precursor for Dragendorff reagent for use in TLC stain and for testing the presence of alkaloids. On silica gel support, it has been reported to be an efficient catalyst for the Biginelli reaction.

Notas

Hygroscopic. Stable. On heating it decomposes to form nitrogen dioxide. Incompatible with strong acids, strong reducing agents, organic materials, and finely powdered metals.

Referencias documentales

Polanki, I. K.; Kurma, S. H.; Bhattacharya, A. K. Direct Glycosylation of Unprotected and Unactivated Sugars Using Bismuth Nitrate Pentahydrate. J. Carbohydr. Chem. 2015, 34 (4), 196-205.

Miersch, L.; Schlesinger, M.; Troff, R. W.; Schalley, C. A.; Rüffer, T.; Heinrich Lang, H.; Zahn, D.; Mehring, M. Hydrolysis of a Basic Bismuth Nitrate-Formation and Stability of Novel Bismuth Oxido Clusters. Chem-Eur. J. 2011, 17 (25), 6985-6990.

Park, Y.; McDonald, K. J.; Choi, K. Progress in Bismuth Vanadate Photoanodes for Use in Solar Water Oxidation. Chem. Soc. Rev. 2013, 42, 2321-2337.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P221-P210-P220-P261-P280-P305+P351+P338-P304+P340-P362-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,1271
Clase de peligro
5.1
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2834.29
TSCA
Yes

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