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7782-61-8 - Iron(III) nitrate hydrate, Puratronic®, 99.999% (metals basis) - 10715 - Alfa Aesar

10715 Iron(III) nitrate hydrate, Puratronic®, 99.999% (metals basis)

Número CAS
7782-61-8
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
5g 92,70
25g 370,80
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Iron(III) nitrate hydrate, Puratronic®, 99.999% (metals basis)

MDL
MFCD00149708
EINECS
233-899-5

Propiedades químicas

Fórmula
Fe(NO3)3•xH2O (x≈9)
Peso molecular
241.86(anhy)
Formulario
Crystalline Aggregates
Punto de fusión
47°
Punto de ebullición
125° dec.
Densidad
1.684
Sensibilidad
Moisture Sensitive
Solubilidad
Soluble in water, alcohol and acetone.

Aplicaciones

It is used as catalyst for the synthesis of sodium amide from sodium and ammonia, and for etching of silver and silver alloys. Ferric nitrate is used in the synthesis of organically templated iron phosphates, and acts as an efficient catalyst in enamination of beta dicarbonyl compounds to beta enaminones. Ferric nitrate impregnated clays are useful as oxidizing agents. Clayfen, produced from ferric nitrate and montmorillonite, is used for the oxidation of thiols to disulfide, and alcohols to aldehydes. Ferric nitrate is useful for regio- and stereo-selective nitration of various aromatic, aliphatic, and heteroaromatic olefins. This reaction provides nitroolefins with excellent E-selectivity. With Keggin-type heteropoly acids, it selectively oxidizes various hydroxy groups.

Notas

Hygroscopic & deliquescent.

Referencias documentales

Paul, A. M.; Khandekar, M. A. C.; Shenoy, A. Silica Supported Ferric Nitrate Nonahydrate: Selective Oxidation of Benzoins Under Mild Conditions. Synthetic Commun. 2003, 33 (15), 2581-2584.

Khajuria, R.; Ambica; Yeshwinder, S.; Kapoor, K. K. Ferric Nitrate Nonahydrate as a Mild and Efficient Catalyst for the Synthesis of β-enaminones. Indian J. Chem. B. 2014, 53B, 1122-1127.

Naveen, T.; Maity, S.; Sharma, U.; Maiti, D. A Predictably Selective Nitration of Olefin with Fe(NO3)3 and TEMPO. J. Org. Chem. 2013, 78, 5949-5954.

Firouzabadi, H.; Iranpoor, N.; Amani, H. Solvent-Free and Selective Oxidation of Hydroxy Groups to their Corresponding Carbonyl Functions with Ferric Nitrate Activated by Heteropoly Acids. Synthesis 2003, 408-412.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H272-H315-H319

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation.

Indicaciones de precaución: P221-P210-P220-P280-P305+P351+P338-P362-P321-P332+P313-P337+P313-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,4027
Clase de peligro
5.1
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2834.29
TSCA
Yes
RTECS
NO7175000

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