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14996-61-3 - Iridium(III) chloride hydrate, 99.8% (metals basis) - 11030 - Alfa Aesar

11030 Iridium(III) chloride hydrate, 99.8% (metals basis)

Número CAS
14996-61-3
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
1g 98,70
5g 368,00
25g 1670,00
50g Pricing available on request. Click Add to Quote Request button and specify size.
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Iridium(III) chloride hydrate, 99.8% (metals basis)

MDL
MFCD00149750
EINECS
233-044-6

Propiedades químicas

Fórmula
IrCl3•xH2O
Peso molecular
298.56(anhy)
Formulario
Crystalline
Solubilidad
Soluble in water and alcohol.

Aplicaciones

Iridium(III) chloride hydrate is used to prepare other iridium compounds. It finds use as a catalyst for oxidation in presence of cerium(IV) and in the the manufacture of electrodes. Iridium(III) chloride is used in iridium electroplating, in making the standard meter bar of Paris and crucibles. It is used for high temperature electrical contacts, as hardening agent, in tipping pens and compass bearings and Pt/Ir spark plugs. It is used for medical, surgical or other patient oriented applications, MMO (mixed metal oxide) titanium electrode coatings and as a starting material for heterogeneous catalysts.

Notas

Hygroscopic and Incompatible with strong oxidants.

Referencias documentales

Botelho, M. B. S.; Hernandez, J. M. F.; Queiroz, T. B.; Eckert, H.; Cola, L.; Camargo, A. S. S. Iridium(iii)-surfactant complex immobilized in mesoporous silica via templated synthesis: a new route to optical materials. J. Mater. Chem. 2011, 21, 8829-8834.

Tandon, P. K. ; Sahgal, S.; Srivastava, M.; Singh, S. B. Catalysis by Ir(III), Rh(III) and Pd(II) metal ions in the oxidation of organic compounds with H2O2. Appl. Organomet. Chem. 2007, 21 (3), 135-138.

Tandon, P. K.; Sahgal, S.; Gayatri; Purwar, M.; Dhusia, M. Oxidation of Ketones by Cerium(IV) in Presence of Iridium(III) Chloride. J. Mol. Catal. A: Chem. 2006, 250 (1-2), 203-209.

Tandon, P. K.; Singh, A. K.; Sahgal, S.; Kumar, S. Oxidation of Cyclic Alcohols by Cerium(IV) in Acidic Medium in the Presence of Iridium(III) chloride. J. Mol. Catal. A: Chem. 2008, 282 (1-2), 136-143.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Indicaciones de precaución: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,5088
Clase de peligro
8
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2843.90
TSCA
Yes

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