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7727-15-3 - Aluminum bromide, 98% - Aluminum tribromide - 11113 - Alfa Aesar

11113 Aluminum bromide, 98%

Número CAS
7727-15-3
Nombre Alternativo
Aluminum tribromide

Tamaño Precio ($) Cantidad Disponibilidad
10g 17,96
100g 91,23
*5x100g 391,40
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Aluminum bromide, 98%

MDL
MFCD00003421
EINECS
231-779-7

Propiedades químicas

Fórmula
AlBr3
Peso molecular
266.71
Formulario
Crystalline
Punto de fusión
97.5°
Punto de ebullición
265°
Densidad
3.21
Sensibilidad
Moisture Sensitive
Solubilidad
Reacts with water violently, soluble in alcohol, carbon disulfide, ether.Slightly soluble in methanol, diethyl ether and acetone.

Aplicaciones

Alkylation, bromination and isomerization catalyst in organic synthesis.Aluminum bromide acts as a strong Lewis acid and is used in Lewis acid-promoted reactions such as epoxide ring openings. It is used as a catalyst for Friedel-Crafts alkylation reaction. It also finds application in bromination and isomerization reactions in organic synthesis. It is also used in polymerization reaction to prepare poly(o-xylene)from benzocyclobutene.

Notas

Hygroscopic in nature. It is incompatible with aqueous solutions, alcohols and acids.

Referencias documentales

Zhou, Y.; Brittain, A. D.; Kong, D.; Xiao, M.; Meng, Y.; Sun, L. Derivatization of diamondoids for functional applications. J. Mater. Chem. C 2015, 3 (27), 6947-6961.

Wang, C.; Hussey, C. L. Aluminum Anodization in the Low-Melting LiAlBr4-NaAlCl4-KAlCl4 Molten Salt. ECS Trans. 2014, 64 (4), 257-265.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H314-H318-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Indicaciones de precaución: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P301+P312-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,332
Clase de peligro
8
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2827.59
TSCA
Yes
RTECS
BD0350000

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