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13453-78-6 - Lithium perchlorate trihydrate, Reagent Grade - 11638 - Alfa Aesar

11638 Lithium perchlorate trihydrate, Reagent Grade

Número CAS
13453-78-6
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
250g 53,25
1kg 149,35
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Lithium perchlorate trihydrate, Reagent Grade

MDL
MFCD00149765
EINECS
232-237-2

Propiedades químicas

Fórmula
ClLiO4•3H2O
Peso molecular
160.45 (106.40anhy)
Formulario
Crystalline
Densidad
1.84
Solubilidad
Highly soluble in water, methanol, ethanol, ethyl acetate, diethyl ether, and acetone.

Aplicaciones

It is used as an oxygen source for chemical oxygen generators, as it liberates oxygen at high temperatures. Excellent solubility of lithium perchlorate permits its use in Diels-Alder reactions. It is also employed in lithium-ion batteries as an electrolyte, and act as chaotropic agent to denature proteins. It is used in Baylis-Hillman reaction as a catalyst in the coupling of alpha,beta-unsaturated carbonyl compounds with aldehydes.

Notas

Hygroscopic. Strong oxidizer and a corrosive solid. Above 400°C, it decomposes to give lithium chloride and oxygen.

Referencias documentales

Qiu, X.; Lu, L.; Leng, J.; Yu, Y.; Wang, W.; Jiang, M.; Bai, L. An enhanced electrochemical platform based on graphene oxide and multi-walled carbon nanotubes nanocomposite for sensitive determination of Sunset Yellow and Tartrazine. Food Chemistry 2016, 190, 889-895.

Toth, P. S.; Dryfe, R. A. W. Novel organic solvents for electrochemistry at the liquid/liquid interface. Analyst 2015, 140, 1947-1954.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P221-P210-P220-P261-P280-P305+P351+P338-P304+P340-P362-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,5539
Clase de peligro
5.1
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2829.90
TSCA
Yes
RTECS
SC8750000

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