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26042-63-7 - Silver hexafluorophosphate, 98% - 11873 - Alfa Aesar

11873 Silver hexafluorophosphate, 98%

Número CAS
26042-63-7
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
1g 35,60
5g 107,00
25g 388,00
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Silver hexafluorophosphate, 98%

MDL
MFCD00003415
EINECS
247-428-6

Propiedades químicas

Fórmula
AgF6P
Peso molecular
252.83
Formulario
Powder
Punto de fusión
102° dec.
Sensibilidad
Light Sensitive
Solubilidad
Soluble in organic solvents such as benzene, toluene, and acetonitrile.

Aplicaciones

It is commonly used as an oxidant forming silver metal. It is often used as a reagent in inorganic and organometallic chemistry. It is used in the preparation of engineering novel materials as well as in preparation of supra molecular Ag(I) complexes. It is used in the development of new catalysts, replacing halide ligands with the weakly coordinating hexafluorophosphate anion.

Notas

Stable under room temperatures and pressures. Moisture sensitive, hygroscopic, and may discolor on exposure to light. Incompatible with strong oxidizing agents and strong acids.

Referencias documentales

Galan, R. F.; Manzano, B. R.; Otero, A.; Lanfranchi, M.; Pellinghelli, M. A. 19F and 31P NMR evidence for silver hexafluorophosphate hydrolysis in solution. New palladium difluorophosphate complexes and x-ray structure determination of [Pd(.eta.3-2-Me-C3H4)(PO2F2)(PCy3)]Inorg. Chem. 1994, 33 (10), 2309-2312.

Hirsch, K. A.; Wilson, S. R.; Moore, J. S. Coordination Networks of 3,3‘-Dicyanodiphenylacetylene and Silver(I) Salts:? Structural Diversity through Changes in Ligand Conformation and Counter ion. Inorg. Chem. 1997, 36 (14), 2960-2968.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H314-H318-H400

Causes severe skin burns and eye damage. Causes serious eye damage. Very toxic to aquatic life.

Indicaciones de precaución: P273-P280-P303+P361+P353-P305+P351+P338-P310

Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Otras referencias

Clase de peligro
8
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2843.29
TSCA
Yes

Recomendado

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    Silver nitrate, ACS, 99.9+% (metals basis)
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    Silver hexafluoroantimonate, 99%
  • 12303

    Cobalt(II) chloride, anhydrous, 99.7% (metals basis)
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    Copper(II) chloride, anhydrous, 98% min
  • 88722

    Silver trifluoromethanesulfonate, 98%

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