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7782-61-8 - Iron(III) nitrate nonahydrate, 98+% (metals basis) - 12226 - Alfa Aesar

12226 Iron(III) nitrate nonahydrate, 98+% (metals basis)

Número CAS
7782-61-8
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
100g 18,54
1kg 43,67
5kg 82,71
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Iron(III) nitrate nonahydrate, 98+% (metals basis)

MDL
MFCD00149708
EINECS
233-899-5

Propiedades químicas

Fórmula
FeN3O9•9H2O
Peso molecular
403.99 (241.86anhy)
Formulario
Crystalline, Contains excess HNO3
Punto de fusión
47°
Punto de ebullición
125° dec.
Densidad
1.684
Sensibilidad
Moisture Sensitive
Solubilidad
Soluble in water, alcohol and acetone.

Aplicaciones

It is used as catalyst for the synthesis of sodium amide from sodium and ammonia, and for etching of silver and silver alloys. Ferric nitrate is used in the synthesis of organically templated iron phosphates, and acts as an efficient catalyst in enamination of beta dicarbonyl compounds to beta enaminones. Ferric nitrate impregnated clays are useful as oxidizing agents. Clayfen, produced from ferric nitrate and montmorillonite, is used for the oxidation of thiols to disulfide, and alcohols to aldehydes. Ferric nitrate is useful for regio- and stereo-selective nitration of various aromatic, aliphatic, and heteroaromatic olefins. This reaction provides nitroolefins with excellent E-selectivity. With Keggin-type heteropoly acids, it selectively oxidizes various hydroxy groups.

Notas

Keep away from materials like organic and powdered metals.

Referencias documentales

Soni, P. A.; Gupta, P. K.; Maurya, C. K.; Halve, A. K.; Ganesan, K. Synthesis of 1,2-diones from 1,2-diols using iron(III) nitrate as oxidant under microwave irradiation. Tetrahedron Lett. 2015, 56 (21), 2817-2819.

Jastrzebski, R.; Van den Berg, E. J.; Weckhuysen, B. M.; Bruijnincx, P. C. A. Sustainable production of dimethyl adipate by non-heme iron(III) catalysed oxidative cleavage of catechol. Catal. Sci. Technol. 2015, 5, 2103-2109.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H272-H315-H319

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation.

Indicaciones de precaución: P221-P210-P220-P280-P305+P351+P338-P362-P321-P332+P313-P337+P313-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,4027
Clase de peligro
5.1
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2834.29
TSCA
Yes
RTECS
NO7175000

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