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7705-08-0 - Iron(III) chloride, anhydrous, 98% - Ferric chloride - 12357 - Alfa Aesar

12357 Iron(III) chloride, anhydrous, 98%

Número CAS
7705-08-0
Nombre Alternativo
Ferric chloride

Tamaño Precio ($) Cantidad Disponibilidad
10g 23,26
100g 29,09
1kg 34,58
5kg 56,62
25kg 222,48
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Iron(III) chloride, anhydrous, 98%

MDL
MFCD00011005
EINECS
231-729-4

Propiedades químicas

Fórmula
Cl3Fe
Peso molecular
162.21
Formulario
Crystalline
Punto de fusión
306°
Punto de ebullición
316°
Densidad
2.90
Sensibilidad
Hygroscopic
Solubilidad
Freely soluble in methanol, ethanol, ether, and acetone.

Aplicaciones

It is used for sewerage treatment of industrial wastes, chloride hydrometallurgy (Silgarin process for the production of silicon), drinking water production, production of precursor for polyvinyl chloride (PVC), and copper-based metals in printed circuit boards. Iron (III) chloride is used as catalyst for the reaction of ethylene with chlorine, as a leaching agent, and as a drying reagent in certain reactions. It is a mild oxidizing agent and converts copper(I) chloride in to copper(II) chloride. As a moderately strong Lewis acid, it catalyzes chlorination of aromatic compounds and Friedel-Crafts reactions. Along with sodium iodide, it brings about reduction of organic azides to corresponding amines. It is useful in the detection of phenols and phenolic derivatives, gamma-hydroxybutyric acids, and also in Trinder spot test for detecting salicylic acids.

Notas

Very sensitive to moisture and corrosive. Incompatible with strong oxidizing agents and forms explosive mixtures with sodium, and potassium.

Referencias documentales

Zhou, Y.; Xing, X. H.; Liu, Z.; Cui, L.; Yu, A.; Feng, Q.; Yang, H. Enhanced coagulation of ferric chloride aided by tannic acid for phosphorus removal from wastewater. Chemosphere 2008, 72 (2), 290-298.

Sarhan, A. A. O.; Bolm, C. Iron(III) chloride in oxidative C-C coupling reactions. Chem. Soc. Rev. 2009, 38, 2730-2744.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H314-H318-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Indicaciones de precaución: P280-P305+P351+P338-P309-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Otras referencias

Merck
14,4019
Clase de peligro
8
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2827.39
TSCA
Yes
RTECS
LJ9100000

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