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429-06-1 - Tetraethylammonium tetrafluoroborate, 99% - A10211 - Alfa Aesar

A10211 Tetraethylammonium tetrafluoroborate, 99%

Número CAS
429-06-1
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
5g 26,00
50g 101,00
100g 180,00
250g 351,00
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Tetraethylammonium tetrafluoroborate, 99%

MDL
MFCD00011827
EINECS
207-055-1

Propiedades químicas

Fórmula
C8H20BF4N
Peso molecular
217.06
Punto de fusión
370-380° dec.
Sensibilidad
Hygroscopic
Solubilidad
Soluble in water, alcohol and acetonitrile.

Aplicaciones

Tetraethylammonium tetrafluoroborate is used as a phase transfer catalyst in organic synthesis. It finds application as an electrolyte additive in the capillary electrophoretic separation of polyphenols found in grape seed extracts. It is also used to prepare other tetrabutylammonium salts in aqueous solutions. It is involved in the synthesis of conducting poly(thiophenes).

Notas

Hygroscopic. Incompatible with strong oxidizing agents.

Referencias documentales

Electrolyte for electro-organic synthesis, e.g. in the o- and p- hydroxylation of simple aromatic ketones, acids and esters by anodic oxidation in TFA: J. Chem. Soc., Chem. Commun., 262 (1975). In CH3CN, the products are the corresponding o- and p-acetamido compounds (cf Ritter reaction).

Use as a supporting electrolyte and F- source for electrochemical fluorination has also been reported: J. Electroanal. Chem., 43, 318 (1973).

Sivaraman, P.; Shashidhara, K.; Thakur, A. P.; Samui, A. B.; Bhattacharyya, A. R. Nanocomposite solid polymer electrolytes based on polyethylene oxide, modified nanoclay, and tetraethylammonium tetrafluoroborate for application in solid-state supercapacitor. Polym. Eng. Sci. 2015, 55 (7), 1536-1545.

Schütter, C.; Ramirez-Castro, C.; Oljaca, M.; Passerini, S.; Winter, M.; Balducci, A. Activated Carbon, Carbon Blacks and Graphene Based Nanoplatelets as Active Materials for Electrochemical Double Layer Capacitors: A Comparative Study. J. Electrochem. Soc. 2015, 162 (1), A44-A51.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H331-H302-H312-H315-H319-H335

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280-P305+P351+P338-P304+P340-P311-P362-P301+P312-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
3917638
Clase de peligro
6.1
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2923.90
TSCA
Yes

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