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130-95-0 - Quinine, anhydrous, 99% (total base), may cont. up to 5% dihydroquinine - A10459 - Alfa Aesar

A10459 Quinine, anhydrous, 99% (total base), may cont. up to 5% dihydroquinine

Número CAS
130-95-0
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
10g 51,40
50g 170,00
250g 670,00
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Quinine, anhydrous, 99% (total base), may cont. up to 5% dihydroquinine

MDL
MFCD00198096
EINECS
205-003-2

Propiedades químicas

Fórmula
C20H24N2O2
Peso molecular
324.42
Punto de fusión
ca 177° dec.
Sensibilidad
Light Sensitive
Solubilidad
Soluble in alcohol, chloroform and diethyl ether. Slightly soluble in water and glycerol.

Aplicaciones

Quinine is used in photochemistry as a common fluorescence standard and as a resolving agent for chiral acids. It is also useful for treating falciparum malaria, lupus, arthritis and vivax malaria. It acts as a flavor component in tonic water and bitter lemon. It is utilized as the chiral moiety for the ligands used in sharpless asymmetric dihydroxylation. Furthermore, it catalyzes the kinetic resolution of furanones.

Notas

Incompatible with strong oxidizing agents.

Referencias documentales

Porta, R.; Benaglia, M.; Coccia, F.; Rossi, S.; Puglisi, A. Enantioselective Organocatalysis in Microreactors: Continuous Flow Synthesis of a (S)-Pregabalin Precursor and (S)-Warfarin. Symmetry 2015, 7 (3), 1395-1409.

Porta, R.; Coccia, F.; Annunziata, R.; Puglisi, A. Comparison of Different Polymer-and Silica-Supported 9-Amino-9-deoxy-epi-quinines as Recyclable Organocatalysts. ChemCatChem 2015, 7 (9), 1490-1499.

Kessler, S.; González, J.; Vlimant, M.; Glauser, G.; Guerin, P. M. Quinine and artesunate inhibit feeding in the African malaria mosquito Anopheles gambiae: the role of gustatory organs within the mouthparts. Physiol. Entomol. 2014, 39 (2), 172-182.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H334-H315-H319-H317-H335

May cause allergy or asthma symptoms or breathing difficulties if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May cause respiratory irritation.

Indicaciones de precaución: P285-P261-P280-P305+P351+P338-P304+P340-P342+P311-P362-P312-P405-P501a

In case of inadequate ventilation wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,8061
Beilstein
91867
Código de tarifa arancelaria unificado
2939.20
TSCA
No
RTECS
VA6020000

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