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79-24-3 - Nitroethane, 99% - A10855 - Alfa Aesar

A10855 Nitroethane, 99%

Número CAS
79-24-3
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
100g 25,49
500g 54,02
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Nitroethane, 99%

MDL
MFCD00007404
EINECS
201-188-9

Propiedades químicas

Fórmula
CH3CH2NO2
Peso molecular
75.07
Punto de fusión
-89°
Punto de ebullición
112-115°
Punto de inflamabilidad
30°(86°F)
Densidad
1.046
Índice de refracción
1.3920
Solubilidad
Soluble in water (4.6 g/100 ml at 20°C).

Aplicaciones

Nitroethane is used as industrial solvents and pharmaceutical intermediates, explosives and as rocket fuel.

Notas

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. It is hygroscopic in nature. Incompatible with oxidizing agents, strong reducing agents, strong acids and strong bases.

Referencias documentales

David J. T. Porters.; Harold J. Bright. Mechanism of Oxidation of Nitroethane by Glucose Oxidase. The Journal Of Biological Chemistry. 1977, 252, (12), 4361-4370.

Syun-ichi Kiyooka.; Yuichi Kaneko.; Ken-ichi Kume. The catalytic asymmetric aldol reaction of silyl ketene acetals with aldehydes in the presence of a chiral borane complex. Nitroethane as a highly effective solvent for catalytic conditions. Tetrahedron Letters. 1992, 33, (34), 4927-4930.

Aldehydes are converted to nitriles in one step in the presence of NaOAc/AcOH (NH4OAc gives the "expected" alkylidene derivative): Synthesis, 510 (1985):

For a review of the use of nitro-compounds as alkyl anion synthons, including methods for removing the nitro-group from the resulting carbon skeletons, see: Synthesis, 833 (1988).

For further reactions of aliphatic nitro-compounds, see Nitromethane, A11806.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H226-H302-H332

Flammable liquid and vapour. Harmful if swallowed. Harmful if inhaled.

Indicaciones de precaución: P210-P261-P280-P240-P241-P303+P361+P353-P304+P340-P301+P312-P312-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,6597
Beilstein
1209324
Clase de peligro
3
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2904.20
TSCA
Yes
RTECS
KI5600000

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