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106-95-6 - Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide - 3-Bromo-1-propene - A11766 - Alfa Aesar

A11766 Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide

Número CAS
106-95-6
Nombre Alternativo
3-Bromo-1-propene

Tamaño Precio ($) Cantidad Disponibilidad
250g 25,20
1000g 68,30
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Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide

MDL
MFCD00000244
EINECS
203-446-6

Propiedades químicas

Fórmula
C3H5Br
Peso molecular
120.98
Punto de fusión
-119°
Punto de ebullición
70-71°
Punto de inflamabilidad
-2°(28°F)
Densidad
1.398
Índice de refracción
1.4700
Sensibilidad
Light Sensitive
Solubilidad
Slightly miscible with water.

Aplicaciones

Allyl bromide is used as an alkylating agent in the synthesis of pharmaceuticals, polymers, adhesives, perfumes, biochemicals and other allylic compounds. It is used as precursor for the preparation of allyliczinc bromide by reacting it with zinc. It is also used in the preparation of allylethers like allyl decyl ether, allyl benzyl ether and allyl geranyl ether. It is also used in the preparation of R enantiomer of allyl phenyl carbinol (APC) such as 1-phenyl-3-butene, which is a valuable intermediate for drugs and agro-chemicals.

Notas

Moisture and light sensitive. Incompatible with oxidizing agents, alkali metals, alkaline earth metals, amides, amines and powdered metals.

Referencias documentales

Pandey, G.; Kant, R.; Batra, S. A general route to the synthesis of indoloazocines using allyl bromides prepared from Morita-Baylis-Hillman adducts. Tetrahedron Lett. 2015, 56 (7), 930-933.

Fananas-Mastral, M.; Vitale, R.; Perez, M.; Feringa, B. L. Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Allylic Alkylation of (Z)-Allyl Bromides with Organolithium Reagents. Chem. Eur. J. 2015, 21 (11), 4209-4212.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H225-H301-H331-H340-H350-H314-H400

Highly flammable liquid and vapour. Toxic if swallowed. Toxic if inhaled. May cause genetic defects. May cause cancer. Causes severe skin burns and eye damage. Very toxic to aquatic life.

Indicaciones de precaución: P210-P260-P201-P261-P301+P310-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,288
Clase de peligro
3
Grupo de embalaje
I
Código de tarifa arancelaria unificado
2903.39
TSCA
Yes
RTECS
UC7090000

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