Cookies disclaimer

Estoy de acuerdo utilizamos cookies para mejorar la experiencia de navegación del usuario y para estudiar cómo se utiliza nuestro sitio web. si navega por nuestro sitio web, estará aceptando el uso de las cookies en las condiciones establecidas en la presente política de cookies. esta política puede ser actualizada, por lo que le invitamos a revisarla de forma regular

556-56-9 - Allyl iodide, 97+%, stab. with copper - 3-Iodo-1-propene - A11822 - Alfa Aesar

A11822 Allyl iodide, 97+%, stab. with copper

Número CAS
556-56-9
Nombre Alternativo
3-Iodo-1-propene

Tamaño Precio ($) Cantidad Disponibilidad
50g 70,20
250g 260,00
Añadir al carrito Añadir al presupuesto al por mayor Ver artículo

Allyl iodide, 97+%, stab. with copper

MDL
MFCD00001094
EINECS
209-130-4

Propiedades químicas

Fórmula
C3H5I
Peso molecular
167.98
Punto de fusión
-99°
Punto de ebullición
101-103°
Punto de inflamabilidad
18°(64°F)
Densidad
1.832
Índice de refracción
1.5540
Sensibilidad
Light Sensitive
Solubilidad
Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water.

Aplicaciones

Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,.

Notas

Store at 4°C. Protect from heat. Store away from oxidizing agents. Incompatible with heat, light, amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Referencias documentales

B. Grzybowska; J. Haber; J. Janas. Interaction of allyl iodide with molybdate catalysts for the selective oxidation of hydrocarbons. Journal of Catalysis.1977, 49 150-163.

Tsuneo Imamoto; Yasuo Hatanaka; Yoshinori Tawarayama; Masataka Yokoyama. Tetrahedron Letters.1981, 49 4987-4988.

Precursor, by reaction with In metal powder, of allylindium reagents which add to alkynes to give 1,4-dienes: J. Org. Chem., 62, 2318 (1997). Allylindiums add to cyclopropenes at the more substituted C atom to give allylcyclopropanes: Tetrahedron Lett., 39, 6317 (1998).

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Indicaciones de precaución: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,294
Beilstein
1697594
Clase de peligro
3
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2903.39
TSCA
Yes
RTECS
UD0450000

Recomendado

  • A10173

    Trifluoromethanesulfonic acid, 98+%
  • A10221

    Imidazole, 99%
  • A11499

    p-Tolyl isothiocyanate, 97%
  • A18236

    (S)-(-)-4-Benzyl-2-oxazolidinone, 99%
  • L08779

    Sodium bis(trimethylsilyl)amide, 1M soln. in THF

Visto recientemente

Productos químicos

Ciencias de la vida

Metales & materiales

Catalizadores

Análisis y material de laboratorio