Cookies disclaimer

Estoy de acuerdo utilizamos cookies para mejorar la experiencia de navegación del usuario y para estudiar cómo se utiliza nuestro sitio web. si navega por nuestro sitio web, estará aceptando el uso de las cookies en las condiciones establecidas en la presente política de cookies. esta política puede ser actualizada, por lo que le invitamos a revisarla de forma regular

17564-64-6 - N-(Chloromethyl)phthalimide, 97% - A12018 - Alfa Aesar

A12018 N-(Chloromethyl)phthalimide, 97%

Número CAS
17564-64-6
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
25g 58,50
100g 221,00
Añadir al carrito Añadir al presupuesto al por mayor Ver artículo

N-(Chloromethyl)phthalimide, 97%

MDL
MFCD00005898
EINECS
241-541-4

Propiedades químicas

Fórmula
C9H6ClNO2
Peso molecular
195.61
Punto de fusión
131-135°
Solubilidad
Insoluble in water.

Aplicaciones

It is used as an agrochemical and medicine intermediates and is used in organic synthesis. Microporous membranes prepared from chemically modified polysulfone, which is a derivative of this compound have better streaming potential.

Notas

Store in cool place. Keep away from oxidizing agents. Incompatible with bases.

Referencias documentales

Ekkehard Hinke.; Eberhard Staude. Streaming potential of microporous membranes made from homogeneously functionalized polysulfone. J. Appl. Polym. Sci. 1991, 42 (11),2951-2958.

M. Hariharan.; S. Chaberek.; A. E. Martella. Synthesis of Phosphonopeptide Derivatives. Synth. Commun. 1973, 3 (5),375-379.

Reagent for carboxyl protection, e.g. in peptide synthesis, by reaction in the presence of an amine: Rec. Trav. Chim., 82, 941 (1963); or with KF in DMF: Synth. Commun., 8, 515 (1978). The phthalimidomethyl ester can be cleaved in various ways including hydrazinolysis, HBr in acetic acid or Zn/AcOH. See also N-(Hydroxymethyl)­phthalimide, B21292 and Appendix 6.

Also reported for the protection of thiols as the S-phthalimidomethyl (Pim) derivative. Cleavage is by hydrazinolysis, followed by Hg(II), Cu(II) or I2: Chem. Lett., 2139 (1994).

Reagent for the amidomethylation of aromatic systems. For reviews of amidomethylation, see: Org. React., 14, 52 (1965); Synthesis, 49 (1970); 85, 181 (1984).

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
140942
Código de tarifa arancelaria unificado
2925.19
TSCA
Yes

Recomendado

Visto recientemente

Productos químicos

Ciencias de la vida

Metales & materiales

Catalizadores

Análisis y material de laboratorio