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25561-30-2 - N,O-Bis(trimethylsilyl)trifluoroacetamide, 98+% - BSTFA - A12033 - Alfa Aesar

A12033 N,O-Bis(trimethylsilyl)trifluoroacetamide, 98+%

Número CAS
25561-30-2
Nombre Alternativo
BSTFA

Tamaño Precio ($) Cantidad Disponibilidad
5g 26,06
10g 34,11
50g 129,78
100g 272,38
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N,O-Bis(trimethylsilyl)trifluoroacetamide, 98+%

MDL
MFCD00008269
EINECS
247-103-9

Propiedades químicas

Fórmula
C8H18F3NOSi2
Peso molecular
257.40
Punto de fusión
-10°
Punto de ebullición
145-147°
Punto de inflamabilidad
23°(73°F)
Densidad
0.97
Índice de refracción
1.3840
Sensibilidad
Moisture Sensitive
Solubilidad
Miscible with chloroform.

Aplicaciones

N,O-Bis(trimethylsilyl)trifluoroacetamide is used as a derivatization reagent for gas chromatography and mass-spectrometry analysis of phenolic acids in fruits. It is also used as a reactant in the preparation of pyrimidinone ribosides and analogs which shows anti-tumor properties. It plays as an important role as a reagent for the regioselective desulfation of polysaccharide sulfates. Furthermore, it is used to prepare trimethylsilyl ethers of carbohydrates and alcohols.

Notas

Moisture sensitive. Store in cool place. Keep the container tightly closed in a dry and well-ventilated place Incompatible with strong oxidizing agents and strong acids.

Referencias documentales

Powerful silylation reagent useful in GC and GC-MS for the derivatization of a wide range of functional groups under mild conditions, similar to N,O-Bis(trimethyl­silyl)­acetamide, L00183, with the advantage that both the reagent and its by-product, trifluoroacetamide, are more volatile than the corresponding non-fluorinated analogues: Biochem. Biophys. Res. Commun., 31, 616 (1968). See Appendix 4.

Sagona, J. A.; Dukett, J. E.; Hawley, H. A.; Mazurek, M. A. Sequential derivatization of polar organic compounds in cloud water using O-(2, 3, 4, 5, 6-pentafluorobenzyl) hydroxylamine hydrochloride, N, O-bis (trimethylsilyl) trifluoroacetamide, and gas-chromatography/mass spectrometry analysis. J. Chromatogr. A 2014, 1362, 16-24.

Irei, S.; Rudolph, J.; Huang, L. Compound-specific stable carbon isotope ratios of phenols and nitrophenols derivatized with N, O-bis (trimethylsilyl) trifluoroacetamide. Anal. Chim. Acta 2013, 786, 95-102.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H314-H318-H226

Causes severe skin burns and eye damage. Causes serious eye damage. Flammable liquid and vapour.

Indicaciones de precaución: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
3607620
Clase de peligro
3
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2931.90
TSCA
No

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