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86-93-1 - 1-Phenyl-1H-tetrazole-5-thiol, 99% - 5-Mercapto-1-phenyl-1H-tetrazole - A12656 - Alfa Aesar

A12656 1-Phenyl-1H-tetrazole-5-thiol, 99%

Número CAS
86-93-1
Nombre Alternativo
5-Mercapto-1-phenyl-1H-tetrazole

Tamaño Precio ($) Cantidad Disponibilidad
25g 34,51
100g 131,84
500g 418,40
Añadir al carrito Añadir al presupuesto al por mayor Ver artículo

1-Phenyl-1H-tetrazole-5-thiol, 99%

MDL
MFCD00003129
EINECS
201-710-5

Propiedades químicas

Fórmula
C7H6N4S
Peso molecular
178.22
Punto de fusión
ca 145° dec.
Punto de inflamabilidad
138°(280°F)
Sensibilidad
Air Sensitive
Solubilidad
Soluble in 5% ethanol, water (partly), acetone, chloroform, and methanol.

Aplicaciones

1-Phenyl-1H-tetrazole-5-thiol is an effective inhibitor of aluminum corrosion in 1M HCl solution. 1-Phenyl-1H-tetrazole-5-thiol was used in the synthesis of oxacyclic building blocks via highly stereoselective radical cyclization and olefin metathesis reactions. It was also used in the synthesis of metalated tetradecyl sulfone. It is also used in the spectrophotometric determination of Pt and Bi.

Notas

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from oxidizing agents.

Referencias documentales

R Cea-Olivares.; OJ Sandoval.; G Espinosa-Perez. New organotin(IV) derivatives of 1-phenyl-1H-tetrazole-5-thiol. Crystal and molecular structure of 1?[Bz3SnSCN4Ph], a polymer built through secondary intermolecular Sn?N bonds. Polyhedron. 2008, 13, (19), 2809-2818.

C Ma.; J Sun. Hydrogen bonding and π-π stacking interaction in the coordination of sulfur and nitrogen donor heterocycle to organotin(IV): syntheses and crystal structures of di- and triorganotin(IV) derivatives with 1-(4-hydroxyphenyl)-1H-tetrazole-5-thiol. Polyhedron. 2004, 23, (9), 2809-2818.

In combination with t-butyl isocyanide, promotes the lactonization of long-chain hydroxy acids: Angew. Chem. Int. Ed., 20, 771 (1981).

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H228

Flammable solid.

Indicaciones de precaución: P210-P280-P240-P241-P370+P378a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.

Otras referencias

Beilstein
139068
Clase de peligro
4.1
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2933.99
TSCA
Yes
RTECS
XF7700000

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