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645-96-5 - Phenylselenol, 90+% - Benzeneselenol - Selenophenol - A12876 - Alfa Aesar

A12876 Phenylselenol, 90+%

Número CAS
645-96-5
Nombre Alternativo
Benzeneselenol
Selenophenol

Tamaño Precio ($) Cantidad Disponibilidad
1g 51,91
5g 186,43
25g 564,80
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Phenylselenol, 90+%

MDL
MFCD00000001
EINECS
211-457-2

Propiedades químicas

Fórmula
C6H6Se
Peso molecular
157.07
Punto de ebullición
71-72°/18mm
Punto de inflamabilidad
70°(158°F)
Densidad
1.479
Índice de refracción
1.6120
Sensibilidad
Air Sensitive
Solubilidad
Not miscible or difficult to mix in water.

Aplicaciones

It is applied for reactions of phenylselenol and its anion. Benzeneselenol can used as starting reagent in the synthesis of monoseleno-substituted 1,3-dienes. It may be used in the synthesis of cationic chalcogenolato-bridged diruthenium complexes.

Notas

Air sensitive. Store away from oxidizing agents and air. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Referencias documentales

Nikolay V Orlov et. al. Exclusive selectivity in the one-pot formation of C-C and C-Se bonds involving Ni-catalyzed alkyne hydroselenation: optimization of the synthetic procedure and a mechanistic study.J Org Chem.,2014,79(24), 12111-12121.

R.J. Puddephatt and P.J. Thompson. Some reactions of methylplatinum and methylgold compounds with phenylselenol, diphenylphosphine, diphenylarsine, N-bromosuccinimide and 2-nitrophenylsulphenyl chloride.J. Organomet. Chem.,1976,117(4), 395-403.

For reactions of phenylselenol and its anion, see Diphenyl­ diselenide, A13919.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H301-H331-H373-H400-H410-H227

Toxic if swallowed. Toxic if inhaled. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Combustible liquid.

Indicaciones de precaución: P210-P260-P261-P273-P280-P301+P310-P304+P340-P311-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
385715
Clase de peligro
6.1
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2931.90
TSCA
Yes

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