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66-71-7 - 1,10-Phenanthroline, 99%, may contain up to 1.5% water - A13163 - Alfa Aesar

A13163 1,10-Phenanthroline, 99%, may contain up to 1.5% water

Número CAS
66-71-7
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
5g 29,90
25g 94,60
100g 268,00
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1,10-Phenanthroline, 99%, may contain up to 1.5% water

MDL
MFCD00011678
EINECS
200-629-2

Propiedades químicas

Fórmula
C12H8N2
Peso molecular
180.21
Punto de fusión
116-119°
Punto de ebullición
>330°
Sensibilidad
Hygroscopic
Solubilidad
Soluble in acetone and ethanol. Slightly soluble in water.

Aplicaciones

1,10-Phenanthroline, anhydrous is used as a chelating agent, used as bidendate nitrogen ligands in Heck type reactions as an alternative to phospine ligands. It is widely used as an indicator for alkyllithium reagents and an inhibitor of metallopeptidase enzymes. It is also used in the analysis formulations in end-user industries like food, beverage and pharmaceuticals.

Notas

Hygroscopic. Incompatible with strong oxidizing agents and strong acids. Store in a tightly closed container. Store in a cool, dry, well-ventilated area.

Referencias documentales

For use as bidentate nitrogen ligands in Heck type reactions as an alternative to phosphine ligands, see: Synlett., 11, 871 (1992).

Indicator for titration of organolithium reagents, giving red charge-transfer complexes, and also in the titration of Grignard reagents: J. Organomet. Chem., 9, 165 (1967); Org. Synth. Coll., 9, 350, 653, 733 (1998).

Reviews: 1,10-Phenanthroline: a versatile ligand: Chem. Soc. Rev., 23, 327 (1994); Coordination compounds as synthetic building blocks: Synlett, 1043 (2002).

Petrov, E. G.; Marchenko, A.; Kapitanchuk, O. L.; Katsonis, N.; Fichou, D. Conductance Mechanism in a Linear Non-Conjugated Trimethylsilyl-Acetylene Molecule: Tunneling Through Localized States. 2014, 589 (1), 3-17.

Wang, Y.; Zhang, Y.; Zhu, D.; Ma, K.; Ni, H.; Tang, G. Synthesis, structural characterization and theoretical approach of the tri(2-(2,6-dichlorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline) cobalt(II). 2015, 147 31-42.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H301-H400-H410

Toxic if swallowed. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Indicaciones de precaución: P273-P264-P270-P301+P310-P321-P330-P391-P405-P501a

Avoid release to the environment. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Specific treatment (see label). Rinse mouth. Collect spillage. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,7214
Beilstein
126461
Clase de peligro
6.1
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2933.99
TSCA
Yes
RTECS
SF8300000

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