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542-05-2 - Acetone-1,3-dicarboxylic acid, 97% - 3-Ketoglutaric acid - 3-Oxoglutaric acid - A13742 - Alfa Aesar

A13742 Acetone-1,3-dicarboxylic acid, 97%

Número CAS
Nombre Alternativo
3-Ketoglutaric acid
3-Oxoglutaric acid

Tamaño Precio ($) Cantidad Disponibilidad
50g 31,60
250g 124,00
1000g 386,00
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Acetone-1,3-dicarboxylic acid, 97%


Propiedades químicas

Peso molecular
Punto de fusión
ca 132° dec.
Soluble in water and alcohol. Slightly soluble in ethyl acetate and ether. Insoluble in chloroform.


Acetone-1,3-dicarboxylic acid is used as a building block in organic chemistry. It is also used in the synthesis of hetrocyclic rings and in the Weiss-Cook reaction, which involves the preparation of cis-bicyclo[3.3.0]octane-3,7-dione by reacting with diacyl (1,2 ketone). Its presence in human urine is used as a diagnostic test for the overgrowth of harmful gut flora such as Candida albicans.


Hygroscopic. Incompatible with strong bases and strong oxidizing agents.

Referencias documentales

For use in Robinson's classical one-step synthesis of pseudopelletierine, see: Org. Synth. Coll., 4, 816 (1963):

For a more recent analogous example of the synthesis of azabicyclo[3.3.1]nonan-3-one derivatives, see: J. Med. Chem., 36, 3707 (1993).

Li, C.; Breit, B. Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of beta-Ketoacids to Allenes: Efficient Construction of Tertiary and Quaternary Carbon Centers. J. Am. Chem. Soc. 2014, 136 (3), 862-865.

Sousa, A.; Araújo, P.; Mateus, N.; de Freitas, V. Deoxyvitisins: a new set of pyrano-3-deoxyanthocyanidins. Tetrahedron Lett. 2013, 54 (35), 4785-4788.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Código de tarifa arancelaria unificado


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    2-Buten-1-ol, cis + trans (ca 1:19), 96%
  • A10755

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  • A11218

    2-Methylcyclohexane-1,3-dione, 98+%
  • A11687

    2,5-Dimethoxytetrahydrofuran, cis + trans, 98%

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