Cookies disclaimer

Estoy de acuerdo utilizamos cookies para mejorar la experiencia de navegación del usuario y para estudiar cómo se utiliza nuestro sitio web. si navega por nuestro sitio web, estará aceptando el uso de las cookies en las condiciones establecidas en la presente política de cookies. esta política puede ser actualizada, por lo que le invitamos a revisarla de forma regular

107-05-1 - Allyl chloride, 98%, stab. with propylene oxide - 3-Chloro-1-propene - A14330 - Alfa Aesar

A14330 Allyl chloride, 98%, stab. with propylene oxide

Número CAS
107-05-1
Nombre Alternativo
3-Chloro-1-propene

Tamaño Precio ($) Cantidad Disponibilidad
100ml 24,30
500ml 39,20
Añadir al carrito Añadir al presupuesto al por mayor Ver artículo

Allyl chloride, 98%, stab. with propylene oxide

MDL
MFCD00000984
EINECS
203-457-6

Propiedades químicas

Fórmula
C3H5Cl
Peso molecular
76.53
Punto de fusión
-135°
Punto de ebullición
44-46°
Punto de inflamabilidad
-28°(-18°F)
Densidad
0.939
Índice de refracción
1.4155
Solubilidad
Soluble in water (3600 mg/L at 20°C), ethanol, ether, petroleum, acetone, chloroform, benzene, methanol and 2-prop.

Aplicaciones

Allyl chloride is used as an alkylating agent. It is used in treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene.

Notas

Store at -20°C. Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong oxidizing agents, boron trifluoride, sulfuric acid and nitric acid

Referencias documentales

Kenji Uneyama.; Nobuyoshi Kamaki.; Akihiko Moriya.; Sigeru Torii. Tin(II)-aluminum-promoted allylation of aldehydes with allyl chloride in an aqueous solvent system. J. Org. Chem. 1985, 50 (25), 5396-5399.

Farley Fisher.; Douglas E. Applequist. Synthesis of 1-Methylcyclopropene. J. Org. Chem. 1965, 30 (6), 2089-2090.

Lithiation with LDA in THF at -78o generatesɑ-chloroallyllithium which can be ɑ-alkylated with primary bromides in high yield. Displacement of the resulting allylic chloride with a dialkyl cuprate to give, stereoselectively, an (E)-alkene, has been used in a pheromone synthesis: J. Org. Chem., 45, 1504 (1981).

Treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene. For details and Diels-Alder reactions, see: J. Org. Chem., 61, 6462 (1996).

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H225-H302-H312-H332-H315-H319-H341-H351-H335-H373

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. Suspected of causing genetic defects. Suspected of causing cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Indicaciones de precaución: P210-P260-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,289
Beilstein
635704
Clase de peligro
3
Grupo de embalaje
I
Código de tarifa arancelaria unificado
2903.29
TSCA
Yes
RTECS
UC7350000

Recomendado

  • A11494

    1-Chlorobutane, 99+%
  • A11766

    Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide
  • A12575

    1-Methylimidazole, 99%
  • A15026

    Allyl alcohol, 98+%
  • 33337

    Magnesium sulfate, anhydrous, 99.5% min

Visto recientemente

Productos químicos

Ciencias de la vida

Metales & materiales

Catalizadores

Análisis y material de laboratorio