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75-03-6 - Iodoethane, 98+%, stab. with copper - Ethyl iodide - A14444 - Alfa Aesar

A14444 Iodoethane, 98+%, stab. with copper

Número CAS
75-03-6
Nombre Alternativo
Ethyl iodide

Tamaño Precio ($) Cantidad Disponibilidad
100g 32,10
500g 112,00
2500g 435,00
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Iodoethane, 98+%, stab. with copper

MDL
MFCD00001091
EINECS
200-833-1

Propiedades químicas

Fórmula
CH3CH2I
Peso molecular
155.97
Punto de fusión
-108°
Punto de ebullición
70-73°
Punto de inflamabilidad
>73°(163°F)
Densidad
1.95
Índice de refracción
1.5120
Sensibilidad
Moisture & Light Sensitive
Solubilidad
Miscible with water.

Aplicaciones

Iodoethane is an excellent ethylating agent used in organic synthesis to introduce an ethyl group into a compound. It reacts with magnesium to form the Grignard reagent, ethylmagnesium iodide which is used in organic synthesis. It is involved in the preparation of 1-ethyl-3-nitro-2-phenyl-indole and also serves as hydrogen radical promoter.

Notas

Moisture and light sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, strong oxidizing agents and magnesium.

Referencias documentales

Nijamudheen, A.; Datta, A. Mechanism for C-I Bond Dissociation in Iodoethane, Iodobenzene, and Iodoethene for the C-C Cross Coupling Reactions over Gold Clusters. J. Phys. Chem. C 2013, 117 (41), 21433-21440.

Ljubic, I.; Matasovic, B.; Bonifacic, M. An efficient buffer-mediated control between free radical substitution and proton-coupled electron transfer: dehalogenation of iodoethane by the alpha-hydroxyethyl radical in aqueous solution. Phys. Chem. Chem. Phys. 2013, 15 (41), 18001-18011.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H302-H315-H319-H334-H317-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation.

Indicaciones de precaución: P284-P261-P280a-P305+P351+P338-P405-P501a

Wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,3813
Beilstein
505934
Código de tarifa arancelaria unificado
2903.39
TSCA
Yes
RTECS
KI4750000

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