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614-16-4 - Benzoylacetonitrile, 98+% - omega-Cyanoacetophenone - beta-Oxohydrocinnamonitrile - A14473 - Alfa Aesar

A14473 Benzoylacetonitrile, 98+%

Número CAS
614-16-4
Nombre Alternativo
omega-Cyanoacetophenone
beta-Oxohydrocinnamonitrile

Tamaño Precio ($) Cantidad Disponibilidad
5g 39,69
25g 133,60
100g 449,60
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Benzoylacetonitrile, 98+%

MDL
MFCD00001942
EINECS
210-369-1

Propiedades químicas

Fórmula
C9H7NO
Peso molecular
145.16
Punto de fusión
79-83°
Punto de ebullición
159-160°/10mm
Solubilidad
Slightly soluble in water.

Aplicaciones

Benzoylacetonitrile is used to produce 2-benzoyl-3-furan-2-yl-acrylonitrile. It is also used in the synthesis of substituted naphtho[1,8-bc]pyrans and as building block in the preparation of 4H-pyrans, 2-pyridones, furans and carbocyclics. It is an active methylene compound, useful in heterocyclic synthesis, e.g. polyfunctional pyridines and pyrimidines.

Notas

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Referencias documentales

L P Davies.; S C Chow.; J H Skerritt.; D J Brown.; G A Johnston. Pyrazolo[3,4-d]pyrimidines as adenosine antagonists.. Life Sciences. 1984, 34 (22), 2117-2128.

Tarek S. Mansour. Hunig's base-magnesium chloride mediated carbon alkylation and oxygen acylation of benzoylacetonitrile. Tetrahedron Letters. 1988, 29 (28), 3437-3440.

Active methylene compound, useful in heterocyclic synthesis, e.g. polyfunctional pyridines and pyrimidines: Synthesis, 775 (1989). Reaction with tosic anhydride, followed by diethyl aminomalonate provides a short, facile synthesis of 3-aminopyrrole-2-carboxylates: J. Org. Chem., 65, 2603 (2000):

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280-P301+P310-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
386745
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2926.90
TSCA
Yes

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