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6294-89-9 - Methyl carbazate, 98% - Methoxycarbonylhydrazine - Methyl hydrazinocarboxylate - A14548 - Alfa Aesar

A14548 Methyl carbazate, 98%

Número CAS
6294-89-9
Nombre Alternativo
Methoxycarbonylhydrazine
Methyl hydrazinocarboxylate

Tamaño Precio ($) Cantidad Disponibilidad
100g 53,90
500g 169,00
2500g 664,00
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Methyl carbazate, 98%

MDL
MFCD00007594
EINECS
228-560-3

Propiedades químicas

Fórmula
C2H6N2O2
Peso molecular
90.08
Punto de fusión
70-73°
Solubilidad
Soluble in water.

Aplicaciones

Methyl carbazate was used in the preparation of methyl 3-(4-methyl-benzyl-idene)carbazate. It was also used in the synthesis of imidazo[1,5-d][1,2,4]triazines. It is used as pharmaceutical intermediate.

Notas

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Referencias documentales

Matsuo Nonoyama. Pyrrole ring cyclopalladation of hydrazones derived from N-(p-toluenesulfonyl)-3-acetylpyrrole with acetylhydrazine, methyl carbazate and semicarbazide. Inorganica Chimica Acta. 1988, 145, (1),53-56

 

R.Truhaut; R.Ferrando; J.M.Faccini; A.M.Monro. Negative results of carcinogenicity bioassay of methyl carbazate in rats: significance for the toxicological evaluation of carbadox. Toxicology. 1981, 22, (3),219-221

Can be used in a sequence for converting ketones to homologated nitriles: Org. Synth. Coll:, 6, 334 (1988):

Alternatively, reaction of the diazene intermediate with MeI and LiOMe yields the ɑ-methylnitrile: J. Org. Chem., 42, 2001 (1977).

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
1679395
Clase de peligro
6.1
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2928.00
TSCA
Yes

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