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107-18-6 - Allyl alcohol, 98+% - 2-Propen-1-ol - 3-Hydroxy-1-propene - A15026 - Alfa Aesar

A15026 Allyl alcohol, 98+%

Número CAS
107-18-6
Nombre Alternativo
2-Propen-1-ol
3-Hydroxy-1-propene

Tamaño Precio ($) Cantidad Disponibilidad
100ml 15,00
500ml 28,20
2500ml 102,00
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Allyl alcohol, 98+%

MDL
MFCD00002920
EINECS
203-470-7

Propiedades químicas

Fórmula
C3H6O
Peso molecular
58.08
Punto de fusión
-129°
Punto de ebullición
95-97°
Punto de inflamabilidad
22°(71°F)
Densidad
0.852
Índice de refracción
1.4130
Solubilidad
Miscible with water.

Aplicaciones

Allyl alcohol is widely used as a precursor to many specialized compounds such as allyl glycidyl ether, allyl diglycidyl carbonate, allyl methacrylate, flame-resistant materials, drying oils and plasticizers. It is used as a raw material for the synthesis of glycerol, glycidyl ethers, esters and amines. It is involved in the synthesis of a variety of polymerizable esters such as diallyl phthalate.

Notas

Incompatible with strong oxidizing agents, acids, oleum and alkali metals. Polymerizes during prolonged storage.

Referencias documentales

Carboxylic acids can be protected as allyl esters, by reaction of allyl alcohol with an activated carboxyl group. They are readily cleaved in the presence of Pd catalysts: J. Org. Chem., 47, 587 (1982); Angew. Chem. Int. Ed., 23, 71 (1984); J. Chem. Soc., Chem. Commun., 1216 (1990).

Harvey, L.; Sánchez, G.; Kennedy, E. M.; Stockenhuber, M. Enhancing allyl alcohol selectivity in the catalytic conversion of glycerol; influence of product distribution on the subsequent epoxidation step. Asia-Pac. J. Chem. 2015, 10 (4), 598-606.

Fukuda, K.; Tojino, M.; Goto, K.; Dohi, H.; Nishida, Y.; Mizuno, M. A recyclable heavy fluorous tag carrying an allyl alcohol pendant group: design and evaluation toward applications in synthetic carbohydrate chemistry. Carbohydr. Res. 2015, 407, 122-130.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H225-H301-H311-H331-H315-H319-H335

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,286
Beilstein
605307
Clase de peligro
6.1
Grupo de embalaje
I
Código de tarifa arancelaria unificado
2905.29
TSCA
Yes
RTECS
BA5075000

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