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626-05-1 - 2,6-Dibromopyridine, 98% - A15397 - Alfa Aesar

A15397 2,6-Dibromopyridine, 98%

Número CAS
626-05-1
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
25g 46,66
100g 160,68
500g 523,20
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2,6-Dibromopyridine, 98%

MDL
MFCD00006223
EINECS
210-926-9

Propiedades químicas

Fórmula
C5H3Br2N
Peso molecular
236.90
Punto de fusión
117-120°
Punto de ebullición
255°
Punto de inflamabilidad
213°(415°F)
Solubilidad
Soluble in hot methanol. Insoluble in water.

Aplicaciones

2,6-Dibromopyridine is used as a tridentate chelating ligand and in the formation of macrocycles containing the terpyridine moiety. It is also used to produce 6-bromo-2-methoxypyridine.

Notas

Incompatible with oxidizing agents. Store in a cool place.

Referencias documentales

Treatment with 4 moles of n-BuLi in ether at -60o, followed by reaction with PCl3 at -40o, provides a useful one-pot synthesis of 6,6"-dibromo-2,2':6',2"-terpyridine, which has applications as a tridentate chelating ligand and in the formation of macrocycles containing the terpyridine moiety: Synthesis, 939 (1995).

/n

Carroll, J.; Gagnier, J. P.; Garner, A. W.; Moots, J. G.; Pike, R. D.; Li, Y.; Huo, S. Reaction of N-Isopropyl-N-phenyl-2,2'-bipyridin-6-amine with K2PtCl4: Selective C-H Bond Activation, C-N Bond Cleavage, and Selective Acylation. Organometallics 2013, 32 (17), 4828-4836.

Prajapati, D.; Schulzke, C.; Kindermann, M. K.; Kapdi, A. R. Selective palladium-catalysed arylation of 2,6-dibromopyridine using N-heterocyclic carbene ligands. RSC Adv. 2015, 5 (65), 53073-53085.

Marcinkowski, D.; Monika Wałęsa-Chorab, M.; Kubicki, M.; Hoffmann, M.; Kądziołka, G.; Michalkiewicz, B.; Patroniak, V. A new 2,6-di(anthracen-9-yl)pyridine ligand and its complexes with Ag(I) ions: Synthesis, structure and photocatalytic activity. Polyhedron 2015, 90, 91-98.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H300-H312-H332-H315-H319-H402-H412

Fatal if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. Harmful to aquatic life. Harmful to aquatic life with long lasting effects.

Indicaciones de precaución: P261-P273-P280-P301+P310-P305+P351+P338-P304+P340-P362-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
108922
Clase de peligro
6.1
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2933.39
TSCA
No
RTECS
US7883000

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