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7440-16-6 - Rhodium, 5% on carbon, dry - A15965 - Alfa Aesar

A15965 Rhodium, 5% on carbon, dry

Número CAS
7440-16-6
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
1g 50,76
5g 178,20
25g 625,60
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Rhodium, 5% on carbon, dry

MDL
MFCD00011201
EINECS
231-125-0

Propiedades químicas

Fórmula
Rh
Solubilidad
Insoluble in water.

Aplicaciones

Rhodium, 5% on carbon is a useful reagent for the conversation of nitriles to primary amines and the hydrogenation of aromatic rings, pyridines, aldehydes and sugars. It is also used for the reduction of oximes to amines and for the reduction of nitrobenzene to phenylhydroxylamine using hydrazine hydrate as the hydrogen source.

Notas

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, halogens, chlorine trifluoride and oxygen difluoride.

Referencias documentales

Joseph J. Mrowca.; Thomas J. Katz. Catalysis of a Cycloaddition Reaction by Rhodium on Carbon. J. Am. Chem. Soc. 1966, 88 (17), 4012-4015 .

Morris Freifelder.; Ralph M. Robinson.; George R. Stone. Hydrogenation of Substituted Pyridines with Rhodium on Carbon Catalyst. J. Org. Chem. 1962, 27 (1), 284-286.

Rhodium catalysts are especially useful for the hydrogenation of aromatic rings under mild conditions. For details for the hydrogenation of 4-aminobenzoic acid to its hexahydro derivative under modest pressure, see: Org. Synth. Coll., 5, 670 (1973).

Rhodium catalysts have also been used for the reduction of oximes to amines.

For a monograph on catalytic hydrogenation, see: P. N. Rylander, Hydrogenation Methods, Academic Press, N.Y. (1985).

For the reduction of nitrobenzene to phenylhydroxylamine using hydrazine hydrate as the hydrogen source, see: Org. Synth. Coll., 8, 16 (1993).

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H228-H315-H319-H335

Flammable solid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P210-P261-P280-P240-P241-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Merck
14,8186
Clase de peligro
4.1
Grupo de embalaje
III
Código de tarifa arancelaria unificado
3815.12
TSCA
Yes
RTECS
VI9069000

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