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355-43-1 - Perfluoro-1-iodohexane, 98+%, stab. with copper - 1-Iodoperfluorohexane - Perfluoro-n-hexyl iodide - B20958 - Alfa Aesar

B20958 Perfluoro-1-iodohexane, 98+%, stab. with copper

Número CAS
355-43-1
Nombre Alternativo
1-Iodoperfluorohexane
Perfluoro-n-hexyl iodide

Tamaño Precio ($) Cantidad Disponibilidad
10g 36,26
50g 132,44
250g 428,00
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Perfluoro-1-iodohexane, 98+%, stab. with copper

MDL
MFCD00001063
EINECS
206-586-6

Propiedades químicas

Fórmula
CF3(CF2)5I
Peso molecular
445.95
Punto de fusión
-45°
Punto de ebullición
117°
Densidad
2.063
Índice de refracción
1.3290
Sensibilidad
Light Sensitive
Solubilidad
Not miscible or difficult to mix in water.

Aplicaciones

It is used as an initiator in the presence of fac-[Ir(ppy) 3 for the photoredox catalyst activated CRP of methacrylates in visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide.

Notas

Light sensitive. Store away from light and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Referencias documentales

Qian Liu, et al. Visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide as the initiator in conjugation with a photoredox catalyst fac-[Ir(ppy)]3.J. Polym. Sci.,2014,52(22), 3283-3291.

Emily R. Berkeley,et al. Syntheses, Structural Characterizations, and Reactivity Studies of Half-Sandwich Cobalt, Rhodium, and Iridium Metallatricarbadecaboranyl Complexes.Organometallics.,2015,34(7), 1396-1407.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
1802118
Código de tarifa arancelaria unificado
2903.78
TSCA
Yes

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