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12150-46-8 - 1,1'-Bis(diphenylphosphino)ferrocene, 97% - Dppf - 1,1'-Ferrocenebis(diphenylphosphine) - B21166 - Alfa Aesar

B21166 1,1'-Bis(diphenylphosphino)ferrocene, 97%

Número CAS
12150-46-8
Nombre Alternativo
Dppf
1,1'-Ferrocenebis(diphenylphosphine)

Tamaño Precio ($) Cantidad Disponibilidad
1g 31,86
5g 97,54
25g 361,06
Añadir al carrito Añadir al presupuesto al por mayor Ver artículo

1,1'-Bis(diphenylphosphino)ferrocene, 97%

MDL
MFCD00001422
EINECS
430-420-3

Propiedades químicas

Fórmula
C34H28FeP2
Peso molecular
554.40
Punto de fusión
ca 182° dec.
Sensibilidad
Air Sensitive
Solubilidad
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Aplicaciones

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Notas

Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Referencias documentales

Hindered bidentate ligand used in, for example, the Ni-catalyzed Suzuki-type crossed coupling of arylboronic acids with aryl mesylates to give biaryls: J. Org. Chem., 60, 1060, 1066 (1995), and of thiophenolates with aryl mesylates to give unsymmetrical diaryl sulfides: J. Org. Chem., 60, 6895 (1995).

Li, C. G.; Xue, F.; Cui, M. J.; Shang, J. Y.; Lou, T. J. 1,1'-bis(diphenylphosphino)ferrocene as an intramolecular or intermolecular bridging ligand related to the phenyl-functionalized diiron propanedithiolate complex: synthesis and catalysis of the reduction of protons. Transition Met. Chem. 2015, 40 (1), 47-52.

Kaur-Ghumaan, S.; Sreenithya, A.; Sunoj, R. B. Synthesis, characterization and DFT studies of 1, 1'-Bis(diphenylphosphino)ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes. J. Chem. Sci. 2015, 127 (3), 557-563.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Código de tarifa arancelaria unificado
2931.90
TSCA
No

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