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37942-07-7 - 3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99% - 3,5-Di-tert-butylsalicylaldehyde - B23834 - Alfa Aesar

B23834 3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99%

Número CAS
37942-07-7
Nombre Alternativo
3,5-Di-tert-butylsalicylaldehyde

Tamaño Precio ($) Cantidad Disponibilidad
5g 47,90
25g 172,00
100g 648,00
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3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99%

MDL
MFCD00191998
EINECS
000-000-0

Propiedades químicas

Fórmula
C15H22O2
Peso molecular
234.34
Punto de fusión
59-61°
Sensibilidad
Air Sensitive
Solubilidad
Soluble in DMSO and methanol.

Aplicaciones

3,5-Di-tert-butyl-2-hydroxybenzaldehyde is used in the synthesis of Mn(III)-salen complex and its diamino precursor 5,6-diamino-5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-β-L-idofuranose, chiral Schiff base ligand for an enantioselective copper-catalyzed addition of phenyl acetylene to imines, chiral oxazolidine ligand for the enantioselective addition of diethyl zinc to aldehydes and tin Schiff base complexes with histidine analogues. It has antibacterial activity and is used in the preparation nickel complexes. It is structurally related to 3,5-di-t-butylcatechol (DTCAT) but is not as potent an activator of rat skeletal muscle ryanodine receptor Ca2+ channel (RyRC).

Notas

Air sensitive. Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Referencias documentales

Yan S and Klemm D. Mild and efficient synthesis of 5, 6-diamino-5, 6-dideoxy-1, 2-O-isopropylidene-3- O -methyl-ß-l-idofuranose: precursor of the first carbohydrate-derived chiral Mn (III)-salen complex. Tetrahedron.,2002,58(50), 10065-10071.

Ariadna Garza-Ortiz, et al. Novel Organotin(IV) Schiff Base Complexes with Histidine Derivatives: Synthesis, Characterization, and Biological Activity.Bioinorg Chem Appl.,2013,2013(6), 502713.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
1877810
Código de tarifa arancelaria unificado
2912.49
TSCA
No

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