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114615-82-6 - Tetra-n-propylammonium perruthenate(VII), 98% - TPAP - B24511 - Alfa Aesar

B24511 Tetra-n-propylammonium perruthenate(VII), 98%

Número CAS
114615-82-6
Nombre Alternativo
TPAP

Tamaño Precio ($) Cantidad Disponibilidad
0.1g 29,44
0.5g 62,62
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Tetra-n-propylammonium perruthenate(VII), 98%

MDL
MFCD00074914

Propiedades químicas

Fórmula
C12H28NO4Ru
Peso molecular
351.43
Punto de fusión
160° dec.
Sensibilidad
Hygroscopic
Solubilidad
Insoluble in water.

Aplicaciones

Tetra-n-propylammonium perruthenate a catalytic oxidant used in conjunction with N-methylmorpholine N-oxide for oxidation of primary & secondary alcohols to aldehydes and ketones.

Notas

Hygroscopic. Store under inert gas. Store away from oxidizing agents, reducing agents, heat, organic materials, metal powders, heat.

Referencias documentales

Huan Cheng; Christian B W Stark. A double donor-activated ruthenium(VII) catalyst: synthesis of enantiomerically pure THF-diols. Angewandte Chemie. International edition in English. 2010, 49 (9), 1587-1590.

Brooks E Maki; Karl A Scheidt. Single-flask synthesis of N-acylated indoles by catalytic dehydrogenative coupling with primary alcohols. Organic Letters. 2009, 11 (7), 1651-1654.

Selective, catalytic oxidant introduced by Ley. Normally used in combination with N-methylmorpholine-N-oxide as the stoichiometric reoxidant and 4A molecular sieves to remove water. Preferred solvents are dichloromethane and acetonitrile. Primary and secondary alcohols are oxidized to aldehydes and ketones in high yield: J. Chem. Soc., Chem. Commun., 1625 (1987). For an example of alcohol to aldehyde oxidation in the partial synthesis of the acyl tetronic acid ionophore tetronasin, see: Tetrahedron Lett., 35, 319 (1994). Also useful for a number of other oxidations such as lactols to lactones and sulfides to sulfones. For oxidation of secondary amines to imines, and of hydroxylamines to nitrones, see: Tetrahedron Lett., 35, 6567, 6571 (1994).

For a comprehensive review of this reagent, see: Synthesis, 639 (1994). For a review of ruthenium oxo-complexes as organic oxidants, see: Chem. Soc. Rev., 21, 179 (1992).

For a brief feature on uses in synthesis, see: Synlett, 824 (2007).

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P221-P210-P220-P261-P280-P305+P351+P338-P304+P340-P362-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Clase de peligro
5.1
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2843.90
TSCA
No

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