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1069-08-5 - Dichloro(diethylamino)phosphine, 97% - (Diethylamino)dichlorophosphine - Diethylphosphoramidous dichloride - H25934 - Alfa Aesar

H25934 Dichloro(diethylamino)phosphine, 97%

Número CAS
1069-08-5
Nombre Alternativo
(Diethylamino)dichlorophosphine
Diethylphosphoramidous dichloride

Tamaño Precio ($) Cantidad Disponibilidad
5g 49,30
25g 138,00
100g 351,00
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Dichloro(diethylamino)phosphine, 97%

MDL
MFCD00013614

Propiedades químicas

Fórmula
C4H10Cl2NP
Peso molecular
174.01
Punto de ebullición
179°
Punto de inflamabilidad
83°(181°F)
Densidad
1.196
Índice de refracción
1.497
Sensibilidad
Moisture Sensitive
Solubilidad
Reacts violently in water.

Aplicaciones

Dichloro(diethylamino)phosphine is used as a reagent for the preparation of diethylaminophosphine-metal complexes and it is a critical starting material in the preparation of various phosphines, phosphoramidites & the phosphitylation of alcohols.

Notas

Moisture sensitive. Store away from oxidizing agents, bases, active metals, water/ moisture.

Referencias documentales

Takeshi Matsumoto and François P. Gabbaï. A Borenium Cation Stabilized by an N-Heterocyclic Carbene Ligand. Organometallics. 2009, 28 (15), 4252-4253.

Kathrin Junge; Günther Oehme; Axel Monsees; Thomas Riermeier; Uwe Dingerdissen; Matthias Beller. Synthesis of new chiral monodentate aminophosphinites and their use in catalytic asymmetric hydrogenations. Journal of Organometallic Chemistry. 2003, 675 (1-2), 91-96.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H314-H318-H227

Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid.

Indicaciones de precaución: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Clase de peligro
8
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2931.90
TSCA
No

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