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97239-80-0 - 1,1'-Bis(diisopropylphosphino)ferrocene, 98% - H27057 - Alfa Aesar

H27057 1,1'-Bis(diisopropylphosphino)ferrocene, 98%

Número CAS
97239-80-0
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
1g 131,00
5g 479,00
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1,1'-Bis(diisopropylphosphino)ferrocene, 98%

MDL
MFCD02684559

Propiedades químicas

Fórmula
C22H36FeP2
Peso molecular
418.34
Punto de fusión
50-52°
Punto de inflamabilidad
>110°(230°F)
Solubilidad
Insoluble in water.

Aplicaciones

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

Notas

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Referencias documentales

Snegur,; L.V.; Simenel,; A. A.; Rodionov,; A. N.; Boev, V. I. Ferrocene modification of organic compounds for medicinal applications. Russ. Chem. Bull. 2014 , 63 26-36.

Joyce H. L. Ong,; Chip Nataro,; James A. Golen,; Arnold L. Rheingold. Electrochemistry of Late Transition Metal Complexes Containing the Ligand 1,1‘-Bis(diisopropylphosphino)ferrocene (dippf) . Organometallics. 2003, 22(24), 5027-5032.

Indicaciones de peligro y de precaución del GHS

Indicaciones de precaución: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Código de tarifa arancelaria unificado
2931.39
TSCA
No

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