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190003-81-7 - (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl - (R)-Xylyl-H8-BINAP - H27351 - Alfa Aesar

H27351 (R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl

Número CAS
190003-81-7
Nombre Alternativo
(R)-Xylyl-H8-BINAP

Tamaño Precio ($) Cantidad Disponibilidad
50mg 128,75
250mg 387,28
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(R)-(+)-2,2'-Bis(di-3,5-xylylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl

MDL
MFCD06796646

Propiedades químicas

Fórmula
C52H56P2
Peso molecular
742.97
Sensibilidad
Air Sensitive
Solubilidad
Insoluble in water.

Aplicaciones

Used in the synthesis of organometallic catalysts. For coupling reactions, addition reactions, asymmetric hydrogenation, asymmetric hydroboration.

Notas

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air.

Referencias documentales

Jianrong (Steve) Zhou,; John F. Hartwig. Intermolecular, Catalytic Asymmetric Hydroamination of Bicyclic Alkenes and Dienes in High Yield and Enantioselectivity. J. Am. Chem. Soc. 2008 , 130 (37),12220-12221.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Código de tarifa arancelaria unificado
2931.90
TSCA
No

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