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33527-91-2 - Tris(2-dimethylaminoethyl)amine, 99+% - Me6TREN - H31853 - Alfa Aesar

H31853 Tris(2-dimethylaminoethyl)amine, 99+%

Número CAS
33527-91-2
Nombre Alternativo
Me6TREN

Tamaño Precio ($) Cantidad Disponibilidad
5g 118,00
25g 394,00
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Tris(2-dimethylaminoethyl)amine, 99+%

MDL
MFCD00015607

Propiedades químicas

Fórmula
C12H30N4
Peso molecular
230.40
Punto de ebullición
70-71°/0.5mm
Índice de refracción
1.4540
Sensibilidad
Air Sensitive & Hygroscopic
Solubilidad
Miscible with water.

Aplicaciones

Tris(2-dimethylaminoethyl)amine is used as an atom transfer radical polymerization (ATRP) ligand for the creation of telechelic polymers. It is a tripodal polyamine ligand and forms complexes with group 1 metals, which is used in alkali-metal-mediated synthetic applications. Further, it is involved in the macrocyclization processes by reacting with tripodal esters in methanol to give tricyclic cryptands.

Notas

Hygroscopic. Air sensitive. Incompatible with oxidizing agents, acids.

Referencias documentales

Samanta, S. R.; Cai, R.; Percec, V. A rational approach to activated polyacrylates and polymethacrylates by using a combination of model reactions and SET-LRP of hexafluoroisopropyl acrylate and methacrylate. Polym. Chem. 2015, 6 (17), 3259-3270.

Citek, C.; Herres-Pawlis, S.; Stack, T. D. P. Low Temperature Syntheses and Reactivity of Cu2O2 Active-Site Models. Acc. Chem. Res. 2015, 48 (8), 2424-2433.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Indicaciones de precaución: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Clase de peligro
8
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2921.29
TSCA
Yes

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