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6088-88-6 - 2-Butenylmagnesium chloride, 0.5M in MeTHF - H51171 - Alfa Aesar

H51171 2-Butenylmagnesium chloride, 0.5M in MeTHF

Número CAS
6088-88-6
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
100ml 181,00
500ml 648,00
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2-Butenylmagnesium chloride, 0.5M in MeTHF

MDL
MFCD01321226

Propiedades químicas

Fórmula
C4H7ClMg
Peso molecular
114.86
Sensibilidad
Air & Moisture Sensitive
Solubilidad
It reacts violently with water.

Aplicaciones

2-Butenylmagnesium chloride is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Notas

Air & moisture sensitive. Incompatible with oxidizing agents and bases.

Referencias documentales

Giuseppe Bartoli; Enrico Marcantoni; Marino Petrini; Renato Dalpozzo. Reaction of aryl and alkyl nitro compounds with 2-butenylmagnesium chloride: synthesis of a new class of nitrones. J. Org. Chem. 1990, 55, (14),4456-4459

 

Motokazu Uemura; Tatsuya Minami; Kazuo Isobe; Toshio Kobayashi; Yuji Hayashi. Diastereoselective addition of 2-butenylmetal “ate” complexes to aromatic ketones mediated by Cr (CO)3 complexation. Tetrahedron Letters. 1986, 27, (8),967-970

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H225-H261-H313-H314-H318

Highly flammable liquid and vapour. In contact with water releases flammable gas. May be harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Indicaciones de precaución: P223-P210-P231+P232-P260u-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Keep away from any possible contact with water, because of violent reaction and possible flash fire. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Clase de peligro
4.3
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2931.90
TSCA
No

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