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185416-17-5 - 3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF - H54781 - Alfa Aesar

H54781 3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

Número CAS
185416-17-5
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
100ml 276,24
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3,5-Dimethyl-4-methoxyphenylmagnesium bromide, 0.5M in 2-MeTHF

MDL
MFCD13319917

Propiedades químicas

Fórmula
C9H11BrMgO
Peso molecular
239.39
Sensibilidad
Air & Moisture Sensitive
Solubilidad
Reacts with water.

Aplicaciones

3,5-Dimethyl-4-methoxyphenylmagnesium bromide is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff fields.

Notas

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases. It is sensitive to air and moisture. Protect from humidity and water. Store under dry inert gas.

Referencias documentales

Tamio Hayashi.; Mitsuo Ishigedani. Rhodium-catalyzed asymmetric arylation of α,β-unsaturated imines with arylstannanes. Catalytic asymmetric synthesis of allylic amines. Tetrahedron. 2001, 57 (13), 2589-2595.

Jin Wook Han.; Tamio Hayashi. Enhanced catalytic activity in asymmetric hydrosilylation of 1,3-dienes with a soluble palladium catalyst. Tetrahedron: Asymmetry. 2002, 13 (3), 325-331.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H225-H314

Highly flammable liquid and vapour. Causes severe skin burns and eye damage.

Indicaciones de precaución: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Clase de peligro
3
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2931.90
TSCA
No

Recomendado

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    4-Phenoxyphenylmagnesium bromide, 0.5 M in 2-MeTHF
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    9-Phenanthrylmagnesium bromide, 0.25 M in 2-MeTHF
  • H54579

    2-Methoxyphenylmagnesium bromide, 1.0 M in 2-MeTHF
  • H54654

    3,4-Dimethoxyphenylmagnesium bromide, 0.5M in THF

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