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89878-14-8 - Diethyl(3-pyridyl)borane, 98% - 3-(Diethylboryl)pyridine - H64225 - Alfa Aesar

H64225 Diethyl(3-pyridyl)borane, 98%

Número CAS
89878-14-8
Nombre Alternativo
3-(Diethylboryl)pyridine

Tamaño Precio ($) Cantidad Disponibilidad
5g 34,10
25g 136,00
100g 546,00
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Diethyl(3-pyridyl)borane, 98%

MDL
MFCD00012348

Propiedades químicas

Fórmula
C9H14BN
Peso molecular
147.03
Punto de fusión
172-175° lit.
Solubilidad
Slightly soluble in water.

Aplicaciones

Reactant for: preparation of inhibitors of ataxia telangiectasia mutated and Rad3 related (ATR) protein kinase as potential anticancer agents, N-Methylation reactions of the pyridyl group, Palladium catalyzed amination reactions, intramolecular Heck reactions, Coupling reactions and Synthesis of trisubstituted pyrimidines from polyhalopyrimidines via Suzuki coupling.

Notas

Store in cool, dry place in tightly closed container. With adequate ventilation. Store away from oxidizing agent.

Referencias documentales

Minoru Ishikura; Tsukasa Ohta; Masanao Terashima. A Novel Synthesis of 4-Aryl-and 4-Heteroarylpyridines via Diethyl (4-pyridyl) borane. Chemical and Pharmaceutical Bulletin.1985 33(11), 4755-4763.

Antonio Guarna; Ernesto G. Occhiato; Fabrizio Machetti; and Vittoria Giacomellia.19-Nor-10-azasteroids. 5.1 A Synthetic Strategy for the Preparation of (+)-17-(3-Pyridyl)-(5β)-10-azaestra-1,16- dien-3-one, a Novel Potential Inhibitor for Human Cytochrome P45017α (17α-Hydroxylase/C17,20-lyase). J. Org. Chem. 1999 64(13),4985-4989.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
4381494
Código de tarifa arancelaria unificado
2933.39
TSCA
No

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