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15186-48-8 - 2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane - 2,2-(R)-Dimethyl-1,3-dioxolane-4-carboxaldehyde - J66337 - Alfa Aesar

J66337 2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane

Número CAS
15186-48-8
Nombre Alternativo
2,2-(R)-Dimethyl-1,3-dioxolane-4-carboxaldehyde

Tamaño Precio ($) Cantidad Disponibilidad
1g 53,55
5g 105,06
10g 200,85
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2,3-O-Isopropylidene-D-glyceraldehyde, 50% w/w in dichloromethane

MDL
MFCD00269682

Propiedades químicas

Fórmula
C6H10O3
Peso molecular
130.14
Formulario
Liquid
Punto de inflamabilidad
62°(144°F)
Índice de refracción
1.454
Solubilidad
Difficult to mix.

Aplicaciones

Reactant involved in organic reactions including, Henry condensation reactions, Synthesis of highly functionalized chiral aziridines, Olefination of aldehydes, C-H oxidations, Aldol-type condensations, Synthesis of hydrophilic pyrazine dyes for use as exogenous fluorescent tracer agents.

Notas

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Referencias documentales

Steinar Hagen.; Thorleif Anthonsen.; Lars Kilaas. Addition of diazomethane and sulfur ylides to the oxo-group in derivatives of ketoses and aldoses : I. Reactions of 2,3-O-isopropylidene-D-glyceraldehyde. Tetrahedron. 1979, 35, (21), 2583-2589.

Brigitte Hafele.; Volker Jager. A Short Synthesis of (S)-5-Hydroxy-2-penten-4-olide from D-Mannitol via 2,3-O-Isopropylidene-D-glyceraldehyde. Liebigs Annalen der Chemie. 1987, 1987, (1), 85-87.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H351-H227

Suspected of causing cancer. Combustible liquid.

Indicaciones de precaución: P210-P201-P280-P281-P202-P308+P313-P370+P378a-P405-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Do not handle until all safety precautions have been read and understood. IF exposed or concerned: Get medical advice/attention. In case of fire: Use for extinction: CO2, powder or water spray. Store locked up. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Clase de peligro
6.1
Grupo de embalaje
III
Código de tarifa arancelaria unificado
2932.99
TSCA
No

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